Product: Co-CUK-1
Synonyms: [Co3(2,4-pdc)2(m3-OH)2]·9H2O (CUK-1; CUK = Cambridge University–KRICT)
CAS：927433-87-2
Basic Information
| Unit MF. | C14H6N2O10Co3 | Unit MW. | 539 | ||
| Coordination Metal | Co | Linkers | 2,4-pyridinedicarboxylic acid, lutidinic acid（CAS：499-80-9） | ||
| Aperture |
0.4 nm |
Pore volume | |||
| Surface Area | NA | ||||
| Analog Structure |  |
||||
Product Property
| Appearance | Brick-Red Powder | |||
| Particle Size | 3-5um irregular bulk particles | |||
Stability
1) CUK-1 is stable in air and acqueous solutions.
2) CUK-1 is flexible according to different solvent and temperature
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for >6 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Hydrogen adsorption, Gas (e.g. carbon dioxide & CH4) and pollutant air adsorption
2) Air separation, one of very few materials capable of separating N2 from O2.
3) With flexible structures in different solvent and temerature, CUK-1 is potential in detecting and sensing for guest moleculars
3) With flexible structures in different solvent and temerature, CUK-1 is potential in detecting and sensing for guest moleculars
Characterizations
References
1）Humphrey, Simon M.; Chang, Jong-San; Jhung, Sung Hwa; Yoon, Ji Woong; Wood, Paul T.; Angew. Chem., Int. Ed. 2007, 46(1+2), 272-275, DOI: 10.1002/anie.200601627 ; Porous cobalt(II)-organic frameworks with corrugated walls: structurally robust gas-sorption materials
2）Yoon, Ji Woong; Jhung, Sung Hwa; Hwang, Young Kyu; Humphrey, Simon M.; Wood, Paul T.; Chang, Jong-San; Advanced Materials 2007, 19(14), 1830-1834, DOI: 10.1002/adma.200601983 ; Gas-sorption selectivity of CUK-1: a porous coordination solid made of cobalt(II) and pyridine-2,4-dicarboxylic acid
3）Lee, Ji Sun; Yoon, Ji Woong; Mileo, Paulo G. M.; Cho, Kyung Ho; Park, Jaedeuk; Kim, Kiwoong; Kim, Hyungjun ; de Lange, Martijn F.; Kapteijn, Freek ; Maurin, Guillaume; Humphrey, Simon M. ; Chang, Jong-San; ACS Applied Materials & Interfaces 2019, 11(29), 25778-25789, DOI: 10.1021/acsami.9b02605 ; Porous metal-organic framework CUK-1 for adsorption heat allocation toward green applications of natural refrigerant water
