Product: MIL-96(Al)
Synonyms: /
CAS：908831-43-6
Basic Information
| Unit MF. | C54H46Al14O62.24H2O | Unit MW. | 2497.02 | ||
| Coordination Metal | Al | Linkers |
Trimesic acid (CAS：554-95-0) |
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| Aperture | 2.5-3.5A | Pore volume | 0.7 cm3/g | ||
| Surface Area | NA | ||||
| Analog Structure |    |
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Product Property
| Appearance | White Powder |  |
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| Particle Size | 1um lenticular paricles | |||
Stability
1) MIL-96(Al) is stable in air, stable in aqueous solutions
2）High thermal stability, thermal decomposition temperature above 300 ° C
2）High thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) For gas adsorption test, it is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (CO2, NH3 e.g.) and pollutant adsorption
2）Lewis acid catalyst or as catalyst for other metal catalysts
2）Lewis acid catalyst or as catalyst for other metal catalysts
3) Addtives or adulteration materials in battery/electrode materials
Characterizations
References
1) Loiseau, Thierry; Lecroq, Ludovic; Volkringer, Christophe; Marrot, Jerome; Ferey, Gerard; Haouas, Mohamed; Taulelle, Francis; Bourrelly, Sandrine; Llewellyn, Philip L.; Latroche, Michel; Journal of the American Chemical Society 2006, 128(31), 10223-10230, DOI: 10.1021/ja0621086 ; MIL-96, a Porous Aluminum Trimesate 3D Structure Constructed from a Hexagonal Network of 18-Membered Rings and μ3-Oxo-Centered Trinuclear Units
2) Benoit, Virginie; Chanut, Nicolas; Pillai, Renjith S.; Benzaqui, Marvin; Beurroies, Isabelle; Devautour-Vinot, Sabine; Serre, Christian; Steunou, Nathalie; Maurin, Guillaume; Llewellyn, Philip L.; Journal of Materials Chemistry A: 2018, 6(5), 2081-2090, DOI: 10.1039/c7ta09696h ; A promising metal-organic framework (MOF), MIL-96(Al), for CO2 separation under humid conditions
3) Zhang, Nantong; Yang, Xuan; Yu, Xinyao; Jia, Yong; Wang, Jin; Kong, Lingtao; Jin, Zhen; Sun, Bai; Luo, Tao; Liu, Jinhuai; Chemical Engineering Journal 2014, 252, 220-229, DOI: 10.1016/j.cej.2014.04.090 ; Al-1,3,5-benzenetricarboxylic metal-organic frameworks: A promising adsorbent for defluoridation of water with pH insensitivity and low aluminum residual
4) Geng, Pengbiao; Wang, Lei; Du, Meng; Bai, Yang; Li, Wenting; Liu, Yanfang; Chen, Shuangqiang; Braunstein, Pierre; Xu, Qiang; Pang, Huan; Advanced Materials 2022, 34(4), 2107836, DOI: 10.1002/adma.202107836 ; MIL-96-Al for Li-S Batteries: Shape or Size
