Product: MOF-74(Ni)
Synonyms: Ni-MOF-74 ; Ni-DOBDC; CPO-27(Ni); Ni2(dhtp)
CAS：882977-00-6
Basic Information
| Unit MF. | C8H4O8Ni2 | Unit MW. | 345.49936 | ||
| Coordination Metal | Ni | Linkers | 2,5-Dihydroxyterephthalic acid (CAS: 610-92-4) | ||
| Aperture |
1.2 nm |
Pore volume | 0.6 cm3/g | ||
| Surface Area | BET Specific surface ＞700 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Brown-Green Powder |  |
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| Particle Size | 3-5um irregular bulk particles | |||
Stability
1) MOF-74(Ni) is stable in air for weeks, but decomposed gradually in wet and hot conditions. It is instable in acqueous solutions.
2）Thermal stability, thermal decomposition temperature above 300 ° C
2）Thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for >6 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (e.g. carbon dioxide & CH4) and pollutant air adsorption
2) MOF-74 is instable in acqueous solutions, thus it could be used for drug adsorption and release
2) MOF-74 is instable in acqueous solutions, thus it could be used for drug adsorption and release
Characterizations
References
1) Dietzel, Pascal D. C.; Panella, Barbara; Hirscher, Michael; Blom, Richard; Fjellvag, Helmer; Chem. Commun., 2006, 959-961, DOI: 10.1039/B515434K ; Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework
2) Zhao, Shenlong; Tan, Chunhui; He, Chun-Ting; An, Pengfei; Xie, Feng; Jiang, Shuai; Zhu, Yanfei; Wu, Kuang-Hsu; Zhang, Binwei ; Li, Haijing; Zhang, Jing; Chen, Yuan ; Liu, Shaoqin; Dong, Juncai ; Tang, Zhiyong; Nat. Energy 2020, 5, 881–890 , DOI: 10.1038/s41560-020-00709-1 ;
Structural transformation of highly active metal-organic framework electrocatalysts during the oxygen evolution reaction
3) Wang, Xiaolu; Xiao, Hai ; Li, Ang; Li, Zhi; Liu, Shoujie; Zhang, Qinghua; Gong, Yue; Zheng, Lirong; Zhu, Youqi; Chen, Chen ; Wang, Dingsheng ; Peng, Qing; Gu, Lin ; Han, Xiaodong ; Li, Jun ; Li, Yadong; J. Am. Chem. Soc. 2018, 140, 45, 15336–15341, DOI: 10.1021/jacs.8b08744 ; Constructing NiCo/Fe3O4 Heteroparticles within MOF-74 for Efficient Oxygen Evolution Reactions
4) Sun, Dengrong; Sun, Fangxiang; Deng, Xiaoyu; Li, Zhaohui; Inorg. Chem. 2015, 54(17), 8639-8643, DOI: 10.1021/acs.inorgchem.5b01278 ; Mixed-Metal Strategy on Metal-Organic Frameworks (MOFs) for Functionalities Expansion: Co Substitution Induces Aerobic Oxidation of Cyclohexene over Inactive Ni-MOF-74
