Product: MOF-74(Ni)
Synonyms: Ni-MOF-74 ; Ni-DOBDC; CPO-27(Ni); Ni2(dhtp)
CAS：882977-00-6
Basic Information
| Unit MF. | C8H4O8Ni2 | Unit MW. | 345.49936 | ||
| Coordination Metal | Ni | Linkers | 2,5-Dihydroxyterephthalic acid (CAS: 610-92-4) | ||
| Aperture |
1.2 nm |
Pore volume | 0.6 cm3/g | ||
| Surface Area | BET Specific surface ＞700 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Brown-Green Powder |  |
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| Particle Size | 3-5um irregular bulk particles | |||
Stability
1) MOF-74(Ni) is stable in air for weeks, but decomposed gradually in wet and hot conditions. It is instable in acqueous solutions.
2）Thermal stability, thermal decomposition temperature above 300 ° C
2）Thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for >6 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (e.g. carbon dioxide & CH4) and pollutant air adsorption
2) MOF-74 is instable in acqueous solutions, thus it could be used for drug adsorption and release
2) MOF-74 is instable in acqueous solutions, thus it could be used for drug adsorption and release
Characterizations
References
1) Dietzel, Pascal D. C.; Panella, Barbara; Hirscher, Michael; Blom, Richard; Fjellvag, Helmer; Chem. Commun., 2006, 959-961, DOI: 10.1039/B515434K ; Hydrogen adsorption in a nickel based coordination polymer with open metal sites in the cylindrical cavities of the desolvated framework
2) Zhao, Shenlong; Tan, Chunhui; He, Chun-Ting; An, Pengfei; Xie, Feng; Jiang, Shuai; Zhu, Yanfei; Wu, Kuang-Hsu; Zhang, Binwei ; Li, Haijing; Zhang, Jing; Chen, Yuan ; Liu, Shaoqin; Dong, Juncai ; Tang, Zhiyong; Nat. Energy 2020, 5, 881–890 , DOI: 10.1038/s41560-020-00709-1 ;
Structural transformation of highly active metal-organic framework electrocatalysts during the oxygen evolution reaction
3) Wang, Xiaolu; Xiao, Hai ; Li, Ang; Li, Zhi; Liu, Shoujie; Zhang, Qinghua; Gong, Yue; Zheng, Lirong; Zhu, Youqi; Chen, Chen ; Wang, Dingsheng ; Peng, Qing; Gu, Lin ; Han, Xiaodong ; Li, Jun ; Li, Yadong; J. Am. Chem. Soc. 2018, 140, 45, 15336–15341, DOI: 10.1021/jacs.8b08744 ; Constructing NiCo/Fe3O4 Heteroparticles within MOF-74 for Efficient Oxygen Evolution Reactions
4) Sun, Dengrong; Sun, Fangxiang; Deng, Xiaoyu; Li, Zhaohui; Inorg. Chem. 2015, 54(17), 8639-8643, DOI: 10.1021/acs.inorgchem.5b01278 ; Mixed-Metal Strategy on Metal-Organic Frameworks (MOFs) for Functionalities Expansion: Co Substitution Induces Aerobic Oxidation of Cyclohexene over Inactive Ni-MOF-74；
5）Jian Zheng, Rama S. Vemuri, Luis Estevez, Phillip K. Koech, Tamas Varga, Donald M. Camaioni, Thomas A. Blake, B. Peter McGrail, Radha Kishan Motkuri; Journal of the American Chemical Society, 2017, 139, 10601-10604; DOI：10.1021/jacs.7b04872; Pore-Engineered Metal−Organic Frameworks with Excellent Adsorption of Water and Fluorocarbon Refrigerant for Cooling Applications；
6) Siru Chen, Ming Xue,* Yanqiang Li, Ying Pan, Liangkui Zhu and Shilun Qiu*; J. Mater. Chem. A, 2015,3, 20145-20152; doi: .1039/C5TA02557E; Rational design and synthesis of NixCo3−xO4 nanoparticles derived from multivariate MOF-74 for supercapacitors;
7) Matthew T. Kapelewski, Tomče Runčevski, Jacob D. Tarver, Henry Z. H. Jiang, Katherine E. Hurst, Philip A. Parilla, Anthony Ayala, Thomas Gennett, Stephen A. FitzGerald, Craig M. Brown, Jeffrey R. Long*; Chemistry of Materials, 2018, 30, 8179-8189; DOI：10.1021/acs.chemmater.8b03276; Record High Hydrogen Storage Capacity in the Metal-Organic Framework Ni₂(m-dobdc) at Near-Ambient Temperatures;
