Product Name：3,3',5,5'-tetrakis(4-carboxyphenyl)-2,2',4,4',6,6'-hexamethyl-1,1'-biphenyl
Synonymous：H4TCHB; H4TTTA;
CAS：868046-56-4
Synonymous：H4TCHB; H4TTTA;
CAS：868046-56-4
Basic Info
| M.F. | C46H38O8 | M.W. | 718.78912 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis：MFM-133(M) (M = Zr, Hf) [r2]
Characterization
Reference
1) Moorthy, J.; Natarajan, R.; Venugopalan, P.; J. Org. Chem. 2005, 70(21), 8568-8571, DOI: 10.1021/jo051205z ; Three-Dimensional Four-Connecting Organic Scaffolds with a Twist: Synthesis and Self-Assembly
2) Yan, Y.; O'Connor, A.; Kanthasamy, G.; Atkinson, G.; Allan, D.; Blake, A.; Schroder, M.; J. Am. Chem. Soc. 2018, 140(11), 3952-3958, DOI: 10.1021/jacs.7b11747 ; Unusual and Tunable Negative Linear Compressibility in the Metal–Organic Framework MFM-133(M) (M = Zr, Hf)
3) Lv, X.; Yuan, S.; Xie, L.; Darke, H.; Chen, Y.; He, T.; Dong, C.; Wang, B.; Zhang, Y.; Li, J.; Zhou, H.; J. Am. Chem. Soc. 2019, 141(26), 10283-10293, DOI:10.1021/jacs.9b02947 ; Ligand Rigidification for Enhancing the Stability of Metal–Organic Frameworks
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