Product Name：4,4'-[1-cyclopentene-1,2-diylbis(5-methyl-4,2-thiophenediyl)]bis-pyridine
Synonymous：BPMTC ; BPDTE；bis(5-pyridyl-2-methylthien-3-yl)cyclopentene
CAS：608528-49-0
Synonymous：BPMTC ; BPDTE；bis(5-pyridyl-2-methylthien-3-yl)cyclopentene
CAS：608528-49-0
Basic Info
| M.F. | C25H22N2S2 | M.W. | 414.58558 | ||
| Appearance |  |
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Properties
1) It is soluble in DMF, DMSO, etc.
2) Sealed storage at room temperature
2) Sealed storage at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:Py-BTE [r2]; Metal-Porphyrin Frameworks porphyrin–BPMTC array [r4]; PC-PCN [r5];
Characterization
Reference
1) Qin, Bing; Yao, Rongxia; Zhao, Xueli; Tian, He; Org. & Biomole. Chem. 2003, 1(12), 2187-2191, DOI: 10.1039/b303028h ; Enhanced photochromism of 1,2-dithienylcyclopentene complexes with metal ion
2) Tian, He; Qin, Bing; Yao, Rongxia; Zhao, Xueli; Yang, Songjie; Adv. Mater. 2003, 15(24), 2104-2107, DOI: 10.1002/adma.200305425 ; A single photochromic molecular switch with four optical outputs probing four inputs
3) Xiao, Shuzhang; Zou, Ying; Wu, Juncheng; Zhou, Yifeng; Yi, Tao; Li, Fuyou; Huang, Chunhui; J. Mater. Chem. 2007, 17(24), 2483-2489, DOI: 10.1039/b701712j ; Hydrogen bonding assisted switchable fluorescence in self-assembled complexes containing diarylethene: controllable fluorescent emission in the solid state
4) Williams, Derek E.; Rietman, Joseph A.; Maier, Josef M.; Tan, Rui; Greytak, Andrew B.; Smith, Mark D.; Krause, Jeanette A.; Shustova, Natalia B.; Journal of the American Chemical Society 2014, 136(34), 11886-11889, DOI: 10.1021/ja505589d ; Energy Transfer on Demand: Photoswitch-Directed Behavior of Metal-Porphyrin Frameworks
5) Park, Jihye; Feng, Dawei; Yuan, Shuai; Zhou, Hong-Cai; Angew. Chem., Int. Ed. 2015, 54(2), 430-435, DOI: 10.1002/anie.201408862 ; Photochromic metal-organic frameworks: Reversible control of singlet oxygen generation
6) Dolgopolova, Ekaterina A.; Galitskiy, Vladimir A.; Martin, Corey R.; Gregory, Haley N.; Yarbrough, Brandon J.; Rice, Allison M.; Berseneva, Anna A.; Ejegbavwo, Otega A.; Stephenson, Kenneth S.; Kittikhunnatham, Preecha; Karakalos, Stavros G.; Smith, Mark D.; Greytak, Andrew B.; Garashchuk, Sophya; Shustova, Natalia B.; Journal of the American Chemical Society 2019, 141(13), 5350-5358, DOI: 10.1021/jacs.8b13853 ; Connecting wires: photoinduced electronic structure modulation in metal-organic frameworks
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