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Tetra(4-anilyl)methane

Tetra(4-anilyl)methane

CAS NO.:60532-63-0Formula:C25H24N4Weight: 380.48486
Product Name:4,4',4'',4'''-Methanetetrayltetraaniline
Synonymous:TAPM; TAM;  MTA
CAS:60532-63-0
Basic Info
M.F.  C25H24N4 M.W.  380.48486
Appearance
Properties
1) 60532-63-0 soluble in EA, DCM, DMF, DMSO, etc.
2) Sealed at 2-8 ℃
Appications
1) It could be used as monomer linker for COF or POF synthesis:3D-Py COF [r4];  COF-300/301/320 [r5, r6];  PI-COF-4 [r7]; PI-1/2; 3D-​TTF-​COF [r1];
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Li, H.; Chang, J. H.; Li, S. S.; Guan, X. Y.; Li, D. H.; Li, C. Y.; Tang, L. X.; Xue, M.; Yan, Y. S.; Valtchev, V.; Qiu, S. L.; Fang, Q. R.  J. Am. Chem. Soc. 2019, 141, 13324, DOI: 10.1021/jacs.9b06908 ; Three-Dimensional Tetrathiafulvalene-Based Covalent Organic Frameworks for Tunable Electrical Conductivity 
2) Ganesan, P.; Yang, X.; Loos, J.; Savenije, T. J.; Abellon, R. D.; Zuilhof, H.;  Sudhölter, E. J. R; J. Am. Chem. Soc. 2005, 127, 14530-14531 DOI: 10.1021/ja053689m ; Tetrahedral n-Type Materials:  Efficient Quenching of the Excitation of p-Type Polymers in Amorphous Films 
3) Wang, Z.; Zhang, B.; Yu, H.; Sun, L.; Jiao, C.; Liu, W. Chem. Commun., 2010,46, 7730-7732 DOI: 10.1039/C0CC02489A ; Microporous polyimide networks with large surface areas and their hydrogenstorage properties
4) Lin, G.; Ding, H.; Yuan, D.; Wang, B.; Wang, C.; DOI:10.1021/jacs.6b00652 ; A Pyrene-Based, Fluorescent Three-Dimensional Covalent Organic Framework
5) Uribe-Romo, F.; Hunt, J.; Furukawa, H.; Kloeck, C.; O'Keeffe, M.; Yaghi, Omar M.; J. Am. Chem. Soc. 2009, 131(13), 4570-4571, DOI:10.1021/ja8096256 ; A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
6) Zhang, Y.; Su, J.; Furukawa, H.; Yun, Y.; Gandara, F.; Duong, A.; Zou, X.; Yaghi, O.;  J. Am. Chem. Soc. 2013, 135(44), 16336-16339, DOI:10.1021/ja409033p ; Single-Crystal Structure of a Covalent Organic Framework
7) Fang, Q.; Wang, J.; Gu, S.; Kaspar, R.; Zhuang, Z.; Zheng, J.; Guo, H.; Qiu, S.; Yan, Y.;  J. Am. Chem. Soc. 2015, 137(26), 8352-8355, DOI:10.1021/jacs.5b04147 ; 3D Porous Crystalline Polyimide Covalent Organic Frameworks for Drug Delivery
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