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benzene-1,3,5- triyltris(methylene))triphosphonic acid

benzene-1,3,5- triyltris(methylene))triphosphonic acid

CAS NO.:586372-53-4Formula:C20H14N4Weight: 310.35196
Product Name:1,​3,​5-​Benzenetris(phosphon​ic acid)​
Synonymous:H6btmp ; H6bmt;P,​P',​P''-​[1,​3,​5-​Benzenetriyltris(met​hylene)​]​tris[phosphonic acid]​; (Benzene-​1,​3,​5-​triyltris(methylene)​)​triphosphonic acid; Mesitylenetriphospho​nic acid
CAS:586372-53-4
Basic Info
M.F. C9H15O9P3 M.W. 360.1314
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:Cu3(btmp)​(H2O)​ [r2]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Jaffres, P.; Villemin, D.; Montouillout, V.; Fernandez, C.; Chardon, J.; Sopkova-De Oliveira Santos, J.; Molecular Crystals and Liquid Crystals Science and Technology, A 2002, 389, 87-95, Self-​association of benzene-​1,​3,​5-​tris-​(methylenephosphonic acid)​: evidence of charge-​assisted hydrogen bonds
2) Yang, C.; Song, Y.; Yeh, Y.; Liu, Y.; Tseng, T.; Lu, K.; CrystEngComm 2011, 13(7), 2678-2686, DOI: 10.1039/c0ce00439a ; A flexible tris-​phosphonate for the design of copper and cobalt coordination polymers: unusual cage array topology and magnetic properties
3) Tang, S.; Pan, X.; Lv, X.; Yan, S.; Xu, X.; Li, L.; Zhao, X.; CrystEngCom 2013, 15(10), 1860-1873, DOI: 10.1039/c2ce26828k ; Fabrication of new metal phosphonates from tritopic trisphosphonic acid containing methyl groups and auxiliary ligands: syntheses, structures and gas adsorption properties
4) Vilela, S.; Firmino, A.; Mendes, R.; Fernandes, J.; Ananias, D.; Valente, A.; Ott, H.; Carlos, L.; Rocha, J.; Tome, J.; Almeida Paz, F.; Chem. Commun. 2013, 49(57), 6400-6402, DOI: 10.1039/c3cc42632g ; Lanthanide-​polyphosphonate coordination polymers combining catalytic and photoluminescence properties