Material Name:[Cu2(bdc)2(bpy)]n
Synonyms:Copper, bis[μ-[1,4-benzenedicarboxylato(2-)-κO1:κO1']](4,4'-bipyridine-κN1)di-
CAS:444902-67-4
Synonyms:Copper, bis[μ-[1,4-benzenedicarboxylato(2-)-κO1:κO1']](4,4'-bipyridine-κN1)di-
CAS:444902-67-4
Structural Information
| Unit Formula | C26H16N2O8CU2 | Molecular Weight | 611.506 | ||
| Coordination Metal | Cu | Linkers |
1,4-benzenedicarboxylate (bdc); 4,4'-bipyridine (bpy) |
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| Pore Size | / | Pore Volume | / | ||
| Surface Area | / | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | / | |||
| Particle Size | 1-5μm | |||
Stability
1) Stable in humid air, stable in water and ethanol
2) Thermal decomposition temperature is greater than 300℃
2) Thermal decomposition temperature is greater than 300℃
Preservation
1) Keep in dry and cool condition
2) It is recommended to activate in a vacuum oven at room temperature for 3 hours before use
Other Features
Fluorescence: Not Available
Applications
1) Gas adsorption and separation (e.g., CO2, SO2)
2) Industrial gas separation (e.g., ethane/ethylene)
2) Industrial gas separation (e.g., ethane/ethylene)
Characterizations
References
1) Yoko Sakata, Shuhei Furukawa, Mio Kondo, Kenji Hirai, Nao Horike, Yohei Takashima, Hiromitsu Uehara, Nicolas Louvain, Mikhail Meilikhov, Takaaki Tsuruoka, Seiji Isoda, Wataru Kosaka, Osami Sakata, Susumu Kitagawa; Science (2013), 339(6116), 193-196, DOI: 10.1126/science.1231451 ; Shape-Memory Nanopores Induced in Coordination Frameworks by Crystal Downsizing；
2) 杜振霞, 何柳青; 一种用于合成柱层式铜基金属一有机框架涂层的电化学方法; 申请公布号 CN 115304777 A, 申请公布日 2022.11.08；
3）Kenji Seki; Phys. Chem. Chem. Phys., 2002, 4, 1968–1971; DOI：10.1039/b110899a; Dynamic channels of a porous coordination polymer responding to external stimuli；
4）Manuel Tsotsalas, Ayako Umemura, Franklin Kim, Yoko Sakata, Julien Reboul, Susumu Kitagawa, Shuhei Furukawa; Journal of Materials Chemistry, 2012, 22, 20; DOI：10.1039/c2jm16333k; Crystal morphology-directed framework orientation in porous coordination polymer films and freestanding membranes via Langmuir–Blodgettry；
5）Hanh T. N. Le, Thuan V. Tran, Nam T. S. Phan, Thanh Truong; Catalysis Science & Technology, 2015, 5, 20; DOI：10.1039/c4cy01074d; Efficient and recyclable Cu₂(BDC)₂(BPY)-catalyzed oxidative amidation of terminal alkynes: role of bipyridine ligand；
6）Guang Lu Han, Ke Zhou, Ao Nan Lai, Qiu Gen Zhang, Ai Mei Zhu, Qing Lin Liu; Journal of Membrane Science, 2014, 454, 36-43; DOI：10.1016/j.memsci.2013.11.049; [Cu₂(bdc)₂(bpy)]ₙ/SPES-C mixed matrix membranes for separation of methanol/methyl tert-butyl ether mixtures
