Product Name：4-[4'-(2,2':6',2''-terpyridil]-boronic acid
Synonymous：trpy-B(OH)2;Boronic acid, (4-[2,2':6',2''-terpyridin]-4'-ylphenyl)-; B-(4-[2,2':6',2''-Terpyridin]-4'-ylphenyl)boronic acid; 4'-(4-Boronatophenyl)-2,2':6',2''-terpyridine
CAS：381218-96-8
3) Wang, Jin-Liang; Li, Xiaopeng; Lu, Xiaocun; Hsieh, I-Fan; Cao, Yan; Moorefield, Charles N.; Wesdemiotis, Chrys; Cheng, Stephen Z. D.; Newkome, George R.; Journal of the American Chemical Society 2011, 133(30), 11450-11453, DOI: 10.1021/ja203645m ; Stoichiometric Self-Assembly of Shape-Persistent 2D Complexes: A Facile Route to a Symmetric Supramacromolecular Spoked Wheel
4) Li, Yiming; Jiang, Zhilong; Wang, Ming; Yuan, Jie; Liu, Die; Yang, Xiaoyu; Chen, Mingzhao; Yan, Jun; Li, Xiaopeng; Wang, Pingshan; 2016, 138(31), 10041-10046, DOI: 10.1021/jacs.6b06021 ; Giant, Hollow 2D Metalloarchitecture: Stepwise Self-Assembly of a Hexagonal Supramolecular Nut
Synonymous：trpy-B(OH)2;Boronic acid, (4-[2,2':6',2''-terpyridin]-4'-ylphenyl)-; B-(4-[2,2':6',2''-Terpyridin]-4'-ylphenyl)boronic acid; 4'-(4-Boronatophenyl)-2,2':6',2''-terpyridine
CAS：381218-96-8
Basic Info
| M.F. | C21H16BN3O2 | M.W. | 353.18164 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It can be used as an intermediate for the synthesis of MOF ligands：[Ru(trpy-B(OH)2)(tb2bpy)Cl](PF6) [r2]
Characterization
Reference
1) Aspley, Catherine J.; Williams, J. A. G.; New J. Chem. 2001, 25(9), 1136-1147, DOI: 10.1039/b103062k ; Palladium-catalysed cross-coupling reactions of ruthenium bis-terpyridyl complexes: strategies for the incorporation and exploitation of boronic acid functionality
2) Altobello, S.; Bignozzi, C. A.; Caramori, S.; Larramona, G.; Quici, Silvio; Marzanni, Giovanni; Lakhmiri, Rajae; J. Photochem. Photobio., A 2004), 166(1-3), 91-98, DOI: 10.1016/j.jphotochem.2004.04.029 ; Sensitization of TiO2 with ruthenium complexes containing boronic acid functions