Product: Co-TTCOF
Synonyms:TTF-Por(Co)-COF
CAS：3015538-22-1
Basic Information
| Unit MF. | C44H32N8Co.C34H20O4S4 | Unit MW. | 1352.49188 | ||
| Linkers |
1) 2,3,6,7-tetra (4-formylphenyl) tetrathiafulvalene (CAS: 1639134-02-3) 2) TAPP-Co(2+)(CAS: 67201-98-3) |
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| Aperture | 1.0 nm and 1.2 nm | Pore volume | 0.72 cm3/g | ||
| Surface Area | BET≥600m²/g | ||||
| Analog Structure |  |
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Product Property
| Appearance | Purple black solid | |||
| Particle Size | ||||
Stability
1) Thermogravimetric analysis (TGA) of TTF Por (Co) - COF under nitrogen atmosphere showed thermal stability up to 400 ° C.
2) TTF Por (Co) - COF exhibits good chemical stability in water and organic solvents.
Preservation
1) Dry and sealed under normal temperature or low temperature conditions ；
2) Suggest using a 100 degree (vacuum) oven for activation for 12 hours before use；
Other Features
Fluorescence:NA
Applications
1) Electrocatalysis, especially in CO2 electrochemical reduction reaction (CO2RR), exhibits a Faraday efficiency of 95% to convert CO2 to CO.
2) Due to its high crystallinity, good porosity, and excellent conductivity, it may have potential applications in fields such as electrocatalysts, energy conversion, and storage.
Characterizations
References
1) Qiao Wu, Rui-Kuan Xie, Min-Jie Mao, Guo-Liang Chai, Jun-Dong Yi, Shao-Shuai Zhao,Yuan-Biao Huang,* and Rong Cao*; ACS Energy Lett. 2020, 5, 1005−1012; DOI: 10.1021/acsenergylett.9b02756; Integration of Strong Electron Transporter Tetrathiafulvalene into Metalloporphyrin-Based Covalent Organic Framework for Highly Efficient Electroreduction of CO2；
