Product：Py-COF
Synonyms：TFPPy‐PyTTA‐COF; Py-Py-COF
CAS：2185790-08-1
Synonyms：TFPPy‐PyTTA‐COF; Py-Py-COF
CAS：2185790-08-1
Basic Information
| Unit MF. | C40H24N2 | Unit MW. | 532.66 | ||
| Linkers |
1,3,6,8-Tetrakis(4-formylphenyl)pyrene (CAS: 1415238-25-3) + 1,3,6,8-Tetrakis(4-aminophenyl)pyrene (CAS: 1610471-69-6) =1:1 Or self-polymerization by BABFPy (1,6-bis(4-formylphenyl)-3,8-bis(4-aminophenyl)pyrene) (CAS: 2375652-84-7) |
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| Aperture | 1.38nm * 1.59nm | Pore volume | NA | ||
| Surface Area | BET Specific surface 1000-1200m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance |
Red or dark orange solid |
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| Particle Size | 50-200nm | |||
Stability
1) Py-COF is stable in air, and stable acqeous solutions (PH 1-14) for days. The BET retains above 500 m2/g after stored for more than 1 year.
2) Thermal decomposition temperature above 400 degree
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) Heated in vacuum at 150 for 2-3 hours
Other Features
Fluorescence: NA
Applications
1) For gas and pollutant adsorption
2) Rigid pores can be used to load other catalysts
2) Rigid pores can be used to load other catalysts
3) Py-COF could be applied as the hole transporting layers in perovskite solar cell
Characterizations
References
1) Y. Li, Q. Chen, T. Xu, Z. Xie, J. Liu, X. Yu, S. Ma, T. Qin, L. Chen, J. Am. Chem. Soc.2019, 141, 13822-13828, DOI: 10.1021/jacs.9b03463 ; De Novo Design and Facile Synthesis of 2D Covalent Organic Frameworks: A Two-in-One Strategy
2) Gao, Y.; Wang, C.; Hu, H.; Ge, R.; Lu, M.; Zhang, J.; Li, Z.; Shao, P.; Jiang, D.; Chem.-Eur. J. 2019, 25(68), 15488-15492, DOI: 10.1002/chem.201904088 ; Synthesis of Two-Dimensional Covalent Organic Frameworks in Ionic Liquids
3) Ascherl, L.; Evans, E.; Hennemann, M.; Di Nuzzo, D.; Hufnagel, A.; Beetz, M.; Friend, R.; Clark, T.; Bein, T.; Auras, F.; Nat. Commun. 2018, 9(1), 1-8, DOI: 10.1038/s41467-018-06161-w ; Solvatochromic covalent organic frameworks
