Product: SIFSIX-14-Cu-i
Synonyms: UTSA-200 ; [Cu(zap)2SiF6-i]
CAS：2119615-01-7
Basic Information
| Unit MF. | C20H16N8F6SiCu | Unit MW. | 574.02 | ||
| Coordination Metal | Cu | Linkers |
(E)-1,2-di(pyridin-4-yl)diazene（CAS：4253-82-1） |
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| Pore Size | 0.24nm | Pore volume | 0.16 cm3/g | ||
| Surface Area | BET: ~ 400m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Grey Purple Powders |  |
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| Particle Size | irregular bulk particles | |||
Stability
1) SIFSIX-14-Cu-i will turn to H2O-SIFSIX-14-i when exposed in humid air for hours.
2) SIFSIX-14-Cu-i is stable in methanol for weeks
2) Thermal decomposition temperature above 200 ° C
2) Thermal decomposition temperature above 200 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate 24 hours at room temperature in vacuum
Other Features
Fluorescence:NA
Applications
1) Gas adsorption (e.g. CO2, SO2)
2）SIFSIX-14-i will release adsrbed gas(e.g. CO2) in humidity, it could be utilized for special gas release.
2) Gas Separation (ethane/ethylene)
2) Gas Separation (ethane/ethylene)
Characterizations
References
1) Debobroto Sensharma, Sebastien Vaesen, Colm Healy, Jens Hartmann, Amal Cherian Kathalikkattil, Paul Wix, Friedrich Steuber, Nianyong Zhu, Wolfgang Schmitt, Eur. J. Inorg. Chem. 2018, 19, 1993-1997, DOI: 10.1002/ejic.201800217 ; CO2 Adsorption in SIFSIX-14-Cu-i: High Performance, Inflected Isotherms, and Water-Triggered Release via Reversible Structural Transformation
2) Dr. Libo Li, Dr. Hui-Min Wen, Chaohui He, Dr. Rui-Biao Lin, Prof. Rajamani Krishna, Dr. Hui Wu, Dr. Wei Zhou, Prof. Jinping Li, Prof. Bin Li, Prof. Banglin Chen, Angew. Chem. Int. Ed. 2018, 57(46), 15183-15188, DOI: 10.1002/anie.201809869 ; A Metal–Organic Framework with Suitable Pore Size and Specific Functional Sites for the Removal of Trace Propyne from Propylene
