Product: 3D-Por-COF
Synonyms: None
CAS：None
Basic Information
| Unit MF. | / | Unit MW. | / | ||
| Linkers |
Tetra(p-aminophenyl)methane (TAPM) 5,10,15,20-tetrakis(4-benzaldehyde)porphyrin (p-Por-CHO) |
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| Pore Size | 0.60nm-1nm | Pore volume | / | ||
| Surface Area | >1000 m²/g | ||||
| Analog Structure | Presumed to be a 2-fold interpenetrated pts topology with Pmc2₁ space group, no corresponding image provided | ||||
Product Property
| Appearance | Deep red powder | |||
| Particle Size | Not mentioned | |||
Stability
1) It shows high stability in common organic solvents, water, and alkaline solutions within 24 hours.
2) Thermal stability: Thermogravimetric analysis indicates high thermal stability up to 500 °C, and the thermal decomposition temperature is not mentioned.
2) Thermal stability: Thermogravimetric analysis indicates high thermal stability up to 500 °C, and the thermal decomposition temperature is not mentioned.
Preservation
1) No special storage conditions are mentioned in the text. Refer to the conventional method: Store in a dry and sealed condition at room temperature or low temperature.
2) Activation method is not mentioned. It can refer to the conventional suggestion: Activate in a vacuum oven at room temperature for 3 hours before use (needs to be verified in practice).
2) Activation method is not mentioned. It can refer to the conventional suggestion: Activate in a vacuum oven at room temperature for 3 hours before use (needs to be verified in practice).
Other Features
1. Fluorescence: Not mentioned.
2. Others: Photosensitive material, can be used as a heterogeneous catalyst to generate singlet oxygen under photoirradiation; shows enhanced photocatalytic activity compared with 3D-CuPor-COF.
2. Others: Photosensitive material, can be used as a heterogeneous catalyst to generate singlet oxygen under photoirradiation; shows enhanced photocatalytic activity compared with 3D-CuPor-COF.
Applications
1) In photocatalysis: It can be used as a heterogeneous photocatalyst to activate molecular oxygen to generate singlet oxygen under photoirradiation.
2) In catalytic research: It provides a research direction for the synthesis of 3D COFs containing other metalloporphyrins for catalytic applications.
2) In catalytic research: It provides a research direction for the synthesis of 3D COFs containing other metalloporphyrins for catalytic applications.
Characterizations
References
1) Lin, Guiqing; Ding, Huimin; Chen, Rufan; Peng, Zhengkang; Wang, Baoshan; Wang, Cheng. Journal of the American Chemical Society, 2017, 139(29), 8705 - 8709, DOI: 10.1021/jacs.7b04141, 3D Porphyrin - Based Covalent Organic Frameworks
