Product: TpTt
Synonyms: TpTt COF；1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with 1,3,5-triazine-2,4,6-triamine
CAS: 2095856-97-4
Basic Information
| Unit MF. | C9H6O6.C3H6N6 | Unit MW. | 336.26 | ||
| Coordination Metal | None | Linkers |
1,3,5-triazine and β-ketoenamine |
||
| Pore Size | ~1.3 nm | Pore Volume | |||
| Surface Area | 277 m2/g | ||||
| Analog Structure | |||||
Product Property
| Appearance | Yellow powders with fibrous morphology | |||
| Particle Size | ||||
Stability
1) Stable under light exposure and can be reused multiple times while maintaining activity
2) Thermal decomposition temperature is greater than 200℃
2) Thermal decomposition temperature is greater than 200℃
Preservation
1) Store in a dry and cool place
2) No special activation method required
Other Features
Strong visible light absorption with peaks at 350 nm and 525 nm
Applications
1) Photocatalytic E-Z isomerization of olefins, used for synthesizing cis-olefins
2) Potential use in visible light-driven organic transformations
2) Potential use in visible light-driven organic transformations
Characterizations
References
1) Mohitosh Bhadra, Sharath Kandambeth, Manoj K. Sahoo, Matthew Addicoat, Ekambaram Balaraman, Rahul Banerjee; J. Am. Chem. Soc. 2019, 141, 6152−6156, DOI: 10.1021/jacs.9b01891 ; Triazine Functionalized Porous Covalent Organic Framework for Photo-organocatalytic E−Z Isomerization of Olefins
2) Mohitosh Bhadra, Sharath Kandambeth, Manoj K. Sahoo, Matthew Addicoat, Ekambaram Balaraman, Rahul Banerjee; Supporting Information for Triazine Functionalized Porous Covalent Organic Framework for Photo-organocatalytic E−Z Isomerization of Olefins
