Product: Ce-UiO-66-NH₂
Synonyms: NH2-UIO-66(Ce)
CAS：2095573-58-1
Basic Information
| Molecular Formular | C48H34Ce6N6O32 | M.W. | 2047.50 | ||
| Coordination Metal | Ce(IV) | Linkers | 2-aminoterephthalic acid | ||
| Pore Size | NA | Pore volume | NA | ||
| Surface Area | >500 m²/g | ||||
| Analog Structure |  |
||||
Product Property
| Appearance | Yellow solid | |||
| Particle Size | NA | |||
Stability
1) Solution stability: NA
2) Thermal stability: NA; Thermal decomposition temperature: NA
2) Thermal stability: NA; Thermal decomposition temperature: NA
Preservation
1) Keep in dry and cool condition
2) Store sealed at room temperature; activate as needed before use
Other Features
Strong visible-light response; remarkable ligand-to-metal charge transfer (LMCT); long excited-state lifetime; photoinduced transient open Ce(III) sites for reversible CO₂ binding; suitable band structure for CO₂ reduction and H₂O oxidation
Applications
1) Visible-light-driven photocatalytic CO₂ reduction to CO with 100% selectivity without sacrificial agents
2) Light-induced reversible CO₂ adsorption and activation for carbon capture and conversion
3) Noble-metal-free photocatalysis for solar-to-chemical conversion coupled with water oxidation
Characterizations
References
1) Shan Dai, Xiangdi Zeng, Benjamin J. Moore, Yuxiang Zhu, Yuhang Yang, Zi Wang, Luyan Li, Te Wang, Ivan da Silva, Luke Keenan, Floriana Tuna, Daniel Lee, Sarah Day, Lucy Saunders, Martin Schröder, Sihai Yang; J. Am. Chem. Soc., 2026, 148, 11749−11757, DOI: 10.1021/jacs.5c20721, Light-Induced Binding and Reduction of CO₂ over Transient Open Ce(III) Sites in a Metal−Organic Framework
