Product: FDMOF-2
Synonyms: NA
CAS：1842361-23-2
Basic Information
| Unit MF. | C22H16N2O8F4Zn2 | Unit MW. | 643.14464 | ||
| Coordination Metal | Zn | Linkers |
2,5-bis(trifluoromethyl)terephthalic acid (BDC-(CF3)2) |
||
| Pore Size | ~5.1 Å | Pore Volume | 0.42 cm3/g | ||
| Surface Area | 1011 m2/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Cuboid | |||
| Particle Size | Not explicitly provided, but the particle size increases compared to FDMOF-1 | |||
Stability
1) Stable in 40% and 70% relative humidity conditions for up to 6 months. No changes in PXRD patterns and minimal changes in N2 adsorption isotherms.
2) Thermal decomposition temperature is above 673 K.
2) Thermal decomposition temperature is above 673 K.
Preservation
1) Store in a dry and cool condition.
2) Activate by heating at room temperature under vacuum for 3 hours.
Other Features
NA
Applications
1) Efficient separation of propane/propylene (C3H8/C3H6) mixtures, even under high humidity conditions, producing high-purity propylene.
2) High adsorption capacity and selectivity for C3H8.
Characterizations
References
1) Yong Wang, Tong Li, Libo Li, Rui-Biao Lin, Xiaoxia Jia, Zeyu Chang, Hui-Min Wen, Xiao-Ming Chen, Jinping Li; Adv. Mater., 2023, 35, 2207955, DOI: 10.1002/adma.202207955; Construction of Fluorinated Propane-Trap in Metal–Organic Frameworks for Record Polymer-Grade Propylene Production under High Humidity Conditions
