Product: COF-TFBD
Synonyms:COF‐I;TFB-BD COF;1,3,5-Benzenetricarboxaldehyde, polymer with [1,1'-biphenyl]-4,4'-diamine
CAS：1817740-08-1
Basic Information
| Unit MF. | C12H12N2.C9H6O3 | Unit MW. | 346.37922 | ||
| Linkers |
1) 1,3,5 triformylbenzene（CAS: 3163-76-6） 2) Benzidine (CAS:92-87-5 ) |
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| Aperture | 1.9 nm | Pore volume | 0.459 cm³g⁻¹ | ||
| Surface Area | BET比表面积约为600-800 m²/g | ||||
| Analog Structure | |||||
Product Property
| Appearance | ||||
| Particle Size | About 1.8 ± 0.2 nm | |||
Stability
1) COF-I is susceptible to damage under changes in pH, temperature, and humidity, indicating poor stability of its structure under external environmental changes.
2) By adjusting the pH value and reaction time, COF-I can achieve reconstruction from disorder to order, demonstrating a certain regenerative ability.
Preservation
1) Dry and sealed under normal temperature or low temperature conditions
2) Before use, its porous structure can be restored by appropriate solvent treatment and pH adjustment.
2) Before use, its porous structure can be restored by appropriate solvent treatment and pH adjustment.
Other Features
Fluorescence:NA
Applications
1) Due to its high specific surface area and adjustable pore structure, COF-I may be suitable for gas adsorption and separation fields.
2) Its reconstruction capability indicates that COF-I may have a longer service life in practical applications, especially in environments that require structural stability and renewability.
Characterizations
References
1) Qiang Gao, Linyi Bai, Yongfei Zeng, Peng Wang, Xiaojing Zhang, Ruqiang Zou,*and Yanli Zhao*; Chem. Eur. J. 2015, 21, 16818 – 16822; DOI : 10.1002/chem.201503053; Reconstruction of Covalent Organic Frameworks by Dynamic Equilibrium;
2) Xueying Kong, Zhongqi Wu, Maria Strømme, and Chao Xu*; J. Am. Chem. Soc. 2024, 146, 1, 742–751; DOI：10.1021/jacs.3c10691; Ambient Aqueous Synthesis of Imine-Linked Covalent Organic Frameworks (COFs) and Fabrication of Freestanding Cellulose Nanofiber@COF Nanopapers;
3) Gong Cheng, Chao Sui,* Weizhe Hao, Jiaxuan Li, Yushun Zhao, Linlin Miao, Guoxin Zhao, Junjiao Li, Yuna Sang, Chenxi Zhao, Lei Wen, Xiaodong He,* and Chao Wang*; Small 2024, 20, 2401635; DOI: 10.1002/smll.202401635; Ultra-Strong Janus Covalent Organic Framework Membrane with Smart Response to Organic Vapor;
