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Home > Product Category > MOF Chemicals > Carboxylic MOFs Linkers > 2d-Carboxylic MOF Linkers > TerPhenyl Linkers & Analogues

2,2''-dimethyl-[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid

2,2''-dimethyl-[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid

CAS NO.:1807547-39-2Formula:C22H18O4Weight: 346.37592
Product Name:2,​2''-​Dimethyl[1,​1':4',​1''-​terphenyl]​-​4,​4''-​dicarboxylic acid
Synonymous:H2Me2BPDC; DMTPDC;2,2″-dimethyl-[1,1′:4′,1″-terphenyl]-4,4″-dicarboxylic acid
CAS:1807547-39-2
Basic Info
M.F. C22H18O4 M.W. 346.37592
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:Cu2(DMTPDC)2(AzoBiPyB) [r2] ; U6-Me2BPDC-8 / Th6-Me2BPDC-8 [r4]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Yu, Xiaojuan; Wang, Zhengbang; Buchholz, Maria; Fuellgrabe, Nena; Grosjean, Sylvain; Bebensee, Fabian; Braese, Stefan; Woell, Christof; Heinke, Lars; Phys. Chem. Chem. Phys. 2015, 17(35), 22721-22725, DOI: 10.1039/C5CP03091A ; cis-​to-​trans isomerization of azobenzene investigated by using thin films of metal-​organic frameworks
2) Wang, Zhengbang; Mueller, Kai; Valasek, Michal; Grosjean, Sylvain; Braese, Stefan; Woell, Christof; Mayor, Marcel; Heinke, Lars; J. Phys. Chem. C 2018, 122(33), 19044-19050, DOI: 10.1021/acs.jpcc.8b05843 ; Series of Photoswitchable Azobenzene-​Containing Metal-​Organic Frameworks with Variable Adsorption Switching Effect
3) Grosjean, Sylvain; Hassan, Zahid; Woell, Christof; Braese, Stefan; Eur. J. Org. Chem. 2019, 2019(7), 1446-1460,
4) Ejegbavwo, Otega A.; Martin, Corey R.; Olorunfemi, Oyindamola A.; Leith, Gabrielle A.; Ly, Richard T.; Rice, Allison M.; Dolgopolova, Ekaterina A.; Smith, Mark D.; Karakalos, Stavros G.; Birkner, Nancy; Powell, Brian A.; Pandey, Shubham; Koch, Robert J.; Misture, Scott T.; Loye, Hans-Conrad zur; Phillpot, Simon R.; Brinkman, Kyle S.; Shustova, Natalia B.; J. Am. Chem. Soc. 2019, 141(29), 11628-11640, DOI: 10.1021/jacs.9b04737 ; Thermodynamics and Electronic Properties of Heterometallic Multinuclear Actinide-​Containing Metal-​Organic Frameworks with "Structural Memory"