Product Name:2,2′,7,7′-tetramethoxy-9,9′-spirobi[fluorene]-3,3′,6,6′-tetracarbaldehyde
Synonymous:TMSFTA;9,9'-Spirobi[9H-fluorene]-3,3',6,6'-tetracarboxaldehyde, 2,2',7,7'-tetramethoxy-
CAS:1801236-33-8
Synonymous:TMSFTA;9,9'-Spirobi[9H-fluorene]-3,3',6,6'-tetracarboxaldehyde, 2,2',7,7'-tetramethoxy-
CAS:1801236-33-8
Basic Info
M.F. | C33H24O8 | M.W. | 548.53886 | ||
Appearance |
Properties
1) It is soluble in DCM,DMF,DMSO,etc.
2) Sealed storage at 2-8 ℃ temperature
2) Sealed storage at 2-8 ℃ temperature
Appications
1) It could be used as monomer linker for COF synthesis:COF-JCU-550,551,552 [r2]
Characterization
Reference
1) Pop, Lidia; Dumitru, Florina; Hadade, Niculina D.; Legrand, Yves-Marie; van der Lee, Arie; Barboiu, Mihail; Grosu, Ion; Org. Lett. 2015), 17(14), 3494-3497, DOI: 10.1021/acs.orglett.5b01576 ; Exclusive Hydrophobic Self-Assembly of Adaptive Solid-State Networks of Octasubstituted 9,9'-Spirobifluorenes
2) Wang, Yujie; Liu, Yaozu; Li, Hui; Guan, Xinyu; Xue, Ming; Yan, Yushan; Valtchev, Valentin; Qiu, Shilun; Fang, Qianrong; J. Am. Chem. Soc. 2020, 142(8), 3736-3741, DOI: 10.1021/jacs.0c00560 ; Three-Dimensional Mesoporous Covalent Organic Frameworks through Steric Hindrance Engineering