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1,3,6,8-Tetrakis(4-aminophenyl)pyrene

1,3,6,8-Tetrakis(4-aminophenyl)pyrene

CAS NO.:1610471-69-6Formula:C40H30N4Weight: 566.693
Product Name:4,4',4'',4'''-(1,3,6,8-pyrenetetrayl)tetrakis- Benzenamine
Synonymous:PyTTA; 1,3,5,8‐tetra(4‐aminophenyl)pyrene
CAS:1610471-69-6
Basic Info
M.F.  C40H30N4 M.W.  566.69
Appearance
Properties
1)  1610471-69-6 soluble in DCM, DMF, DMSO, etc.
2)  2-8 ℃ sealed storage
Appications
1) It could be used as monomer linker for COF synthesis:Py-Py-COF [r5]; TTF-Py-COF [r1]; PyTTA-BFBIm-iCOF; VO-​PyTTA-​2,​3-​DHTA [r3]; Py-DHPh COF [r2]; TAPPy‐PDA [r4]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Jin, S.; Sakurai, T.; Kowalczyk, T.;  Dalapati, S.; Xu,  F.; Wei, H.; Chen, X.;  Gao, J.; Seki, S.; Irle, S.; Jiang, D.;  Chem. -Eur. J. 2014, 20, 14608-14613, DOI:10.1002/chem.201402844
2) Chen, X.; Huang, N.; Gao, J.; Xu, H.; Xu, F.; Jiang, D.; Chem. Commun., 2014,50, 6161-6163, DOI: 10.1039/C4CC01825G ; Towards covalent organic frameworks with predesignable and aligned open docking sites 
3) Vardhan, H.; Hou, L.; Yee, E.; Nafady, A.; Al-Abdrabalnabi, M.; Al-Enizi, A.; Pan, Y.; Yang, Z.; Ma, S.; ACS Sustainable Chem. Eng. 2019, 7, 5, 4878-4888, DOI: 10.1021/acssuschemeng.8b05373 ; Vanadium Docked Covalent-Organic Frameworks: An Effective Heterogeneous Catalyst for Modified Mannich-Type Reaction 
4) Feriante, C.; Jhulki, S.; Evans, A.; Dasari, R.; Slicker, K.; Dichtel, W.; Marder, S.; Adv. Mater. 2020, 32(2), 1905776, DOI:10.1002/adma.201905776 ;Rapid Synthesis of High Surface Area Imine‐Linked 2D Covalent Organic Frameworks by Avoiding Pore Collapse During Isolation
5) Ascherl,Laura; Evans,Emrys W.;  Hennemann,Matthias;  Di Nuzzo,Daniele;  Hufnagel,Alexander G.; Beetz, Michael;  Friend,Richard H.; Clark,Timothy;  Bein, Thomas;  Auras, Florian; Nat. Commun. 2018, 9, 3802, DOI: 10.1038/s41467-018-06161-w ; Solvatochromic covalent organic frameworks
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