Product: TpPa-NO2
Synonyms: NA
CAS：NA
Basic Information
| Unit MF. | NA | Unit MW. | NA | ||
| Linkers | |||||
| Pore Size | 1.5 nm | Pore volume | NA | ||
| Surface Area | >300 m²/g | ||||
| Analog Structure | NA | ||||
Product Property
| Appearance | dark reddish solid | |||
| Particle Size | irregular cluster particles | |||
Stability
1) In aqueous solutions, stable in boiling water (100°C) for 7 days; stable in strong acids such as 12M HCl and 2M H₂SO₄ for 1 week, and stable in 0.1M NaOH alkaline aqueous solution for 24 hours; .
2) Thermal stability: stable at 300°C and starts to decompose after 350°C .
2) Thermal stability: stable at 300°C and starts to decompose after 350°C .
Preservation
1) Store at room temperature and keep dry.
Other Features
Fluorescence: NA;
Applications
1) Gas adsorption and separation: Selectively separate C₂H₄ from a C₂H₂/C₂H₄/CO₂ mixture and capture CO₂ from CO₂/N₂.
2) Removal of heavy metal ions: Used to adsorb various heavy metal ions after reduction and modification .
2) Removal of heavy metal ions: Used to adsorb various heavy metal ions after reduction and modification .
Characterizations
References
1) Suman Chandra, Sharath Kandambeth, Bishnu P. Biswal, Binit Lukose, Shrikant M. Kunjir, Minakshi Chaudhary, Ravichandar Babarao, Thomas Heine, Rahul Banerjee; Journal of the American Chemical Society 2013, 135(47), 17853 - 17861, DOI: 10.1021/ja408121p ; Chemically Stable Multilayered Covalent Organic Nanosheets from Covalent Organic Frameworks via Mechanical Delamination
2) Yunzhe Jiang, Chuanyao Liu, Aisheng Huang; ACS Applied Materials & Interfaces 2019, DOI: 10.1021/acsami.9b11850 ; EDTA - Functionalized Covalent Organic Framework for Removal of Heavy Metal Ions
3) Xiao - Hong Xiong, Liang Zhang, Wei Wang, Neng - Xiu Zhu, Lu - Zhu Qin, Huan - Feng Huang, Liu - Li Meng, Yang - Yang Xiong, Mihail Barboiu, Dieter Fenske, Peng Hu, Zhang - Wen Wei; ACS Applied Materials & Interfaces 2022, 14(30), 32105 - 32111, DOI: 10.1021/acsami.2c08338 ; Nitro - Decorated Microporous Covalent Organic Framework (TpPa - NO2) for Selective Separation of C2H4 from a C2H2/C2H4/CO2 Mixture and CO2 Capture
4) Weiliang Jin, Shaocong Li, Hongzhi Zhou, Shenghua Ma, Lina Zhu, Deming Kong; Advanced Functional Materials 2024, 34(2406834), DOI: 10.1002/adfm.202406834 ; Pore Wall Engineered Polar COFs as Size - Matched Nanotraps Enable Highly Efficient Capture of Long - Chain Alkylamines
