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Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetrakis(4-bromophenyl)-

Tricyclo[3.3.1.13,7]decane, 1,3,5,7-tetrakis(4-bromophenyl)-

CAS NO.:144970-36-5Formula:C34H28Br4Weight: 756.20212
Product Name:1,3,5,7-tetrakis(4-bromophenyl)adamatane
Synonymous:TBAD; TBPA; TBA
CAS:144970-36-5
Basic Info
M.F. C34H28Br4 M.W. 756.20212
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It can be used as an intermediate to synthesize POP materials : PPN-3 [r2], MOP-​Ad [r3], NUS-23 [r4], NPN-3 [r5]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Holst, James R.; Stockel, Ev; Adams, Dave J.; Cooper, Andrew I.; Macromolecules 2010, 43, 20, 8531-8538, DOI: 10.1021/ma101677t
2) Lu, W.; Yuan, D.; Zhao, D.; Schilling, C.; Plietzsch, O.; Muller, T.; Brase, S.; Guenther, J.; Blumel, J.; Krishna, R.; Li, .; Zhou, H.; Chem. Mater. 2010, 22, 21, 5964–5972, DOI: 10.1021/cm1021068
3) Li, X.; Guo, J.; Yue, H.; Wang, J.; Topham, P.; RSC Advances 2017, 7(26), 16174-16180, DOI: 10.1039/C6RA28833B
4) Dong, J.; Tummanapelli, A.; Li, X.; Ying, S.; Hirao, H.; Zhao, D.; Chem. Mater. 2016, 28, 21, 7889-7897, DOI: 10.1021/acs.chemmater.6b03376
5) Beaudoin, D.; Maris, T.; Wuest, J.; Nat. Chem. 2013, 5(10), 830-834, DOI: 10.1038/nchem.1730