Product Name:1,3,5,7-Tetrakis(4-iodophenyl)adamantane
Synonymous:TIPA;1,3,5,7-Tetrakis(4-iodophenyl)tricyclo[3.3.1.13,7]decan ; 1,3,5,7-Tetrakis(p-iodophenyl)adamantane
CAS:144970-30-9
3) Wang, Shujun; Oldham, Warren J., Jr.; Hudack, Raymond A., Jr.; Bazan, Guillermo C.; Journal of the American Chemical Society 2000, 122(24), 5695-5709, DOI: 10.1021/ja992924w ; Synthesis, Morphology, and Optical Properties of Tetrahedral Oligo(phenylenevinylene) Materials
Synonymous:TIPA;1,3,5,7-Tetrakis(4-iodophenyl)tricyclo[3.3.1.13,7]decan ; 1,3,5,7-Tetrakis(p-iodophenyl)adamantane
CAS:144970-30-9
Basic Info
M.F. | C34H28I4 | M.W. | 944.20212 | ||
Appearance |
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It can be used as an intermediate to synthesize MOF ligands or COF monomers:PAFad [r5]
Characterization
Reference
1) Mathias, Lon J.; Reichert, Veronica R.; Muir, Andrew V. G.; Chem. Mater. 1993, 5(1), 4-5, DOI: 10.1021/cm00025a002 ; Synthesis of rigid tetrahedral tetrafunctional molecules from 1,3,5,7-tetrakis(4-iodophenyl)adamantane
2) Lu, Weigang; Yuan, Daqiang; Zhao, Dan; Schilling, Christine Inge; Plietzsch, Oliver; Muller, Thierry; Brase, Stefan; Guenther, Johannes; Blumel, Janet; Krishna, Rajamani; Li, Zhen; Zhou, Hong-Cai; Chem. Mater. 2010, 22(21), 5964-5972, DOI: 10.1021/cm1021068 ; Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage/Separation4) Xie, Lin-Hua; Suh, Myunghyun Paik; Chem. Eur. J. 2013, 19(35), 11590-11597, DOI: 10.1002/chem.201301822 ; High CO2-Capture Ability of a Porous Organic Polymer Bifunctionalized with Carboxy and Triazole Groups
5) Verde-Sesto, Ester; Merino, Estibaliz; Rangel-Rangel, Elizabeth; Corma, Avelino; Iglesias, Marta; Sanchez, Felix; ACS Sustainable Chem. & Eng. 2016, 4(3), 1078-1084, DOI: 10.1021/acssuschemeng.5b01147 ; Postfunctionalized Porous Polymeric Aromatic Frameworks with an Organocatalyst and a Transition Metal Catalyst for Tandem Condensation-Hydrogenation Reactions