Product: ZIF-62
Synonyms: Zn-ZIF-62; [μ-(1H-Benzimidazolato-κN1:κN3)]bis[μ-(1H-imidazolato-κN1:κN3)]pentakis(1H-imidazolato-κN1)tetrazinc
CAS：1446434-44-1
Basic Information
| Unit MF. | C28H26N16Zn4 | Unit MW. | 848.17324 | ||
| Coordination Metal | Zn | Linkers | 1H-imidazole (CAS: 288-32-4) ：1H-benzimidazole（CAS：51-17-2） =7:1 | ||
| Pore Size | Pore volume | ||||
| Surface Area | No adsoptive capability | ||||
| Analog Structure |   |
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Product Property
| Appearance | White Crystals |  |
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| Particle Size | ||||
Stability
1) ZIF-62 is air stable, with high thermal stability and thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) No neccesary for activation
2) No neccesary for activation
Other Features
Fluorescence:NA
Applications
1) ZIF-62 is of glass form, which could be applied in research of opitcal appliance and sensors.
Characterizations
References
1) Gustafsson, M.; Zou, X.; J. Porous Mater. 2013, 20(1), 55-63, DOI: 10.1007/s10934-012-9574-1 ; Crystal formation and size control of zeolitic imidazolate frameworks with mixed imidazolate linkers
2) Bennett, T.; Yue, Y.; Li, P.; Qiao, A.; Tao, H.; Greaves, N.; Richards, T.; Lampronti, G.; Redfern, S.; Blanc, F.; Farha, O.; Hupp, J.; Cheetham, A.; Keen, D.; J. Am. Chem. Soc. 2016, 138(10), 3484-3492, DOI: 10.1021/jacs.5b13220 ; Melt-Quenched Glasses of Metal–Organic Frameworks
3) Qiao, A.; Bennett, T.; Tao, H.; Krajnc, A.; Mali, G.; Doherty, C.; Thornton, A.; Mauro, J.; Greaves, G.; Yue, Y.; Sci. Adv. 2018, 4(3), eaao6827/1-eaao6827/7, DOI: 10.1126/sciadv.aao6827 ; A metal-organic framework with ultrahigh glass-forming ability
4) Rasmus S. K. Madsen, Ang Qiao, Jishnu Sen, Ivan Hung, Kuizhi Chen, Zhehong Gan, Sabyasachi Sen, Yuanzheng Yue; Science 2020, 367,1473-1476, DOI: 10.1126/science.aaz0251 ; Ultrahigh-field 67Zn NMR reveals short-range disorder in zeolitic imidazolate framework glasses ;
