Product: Mg2(dobpdc)
Synonyms: Mg-IRMOF-74-II
CAS：1433849-68-3
Basic Information
| Unit MF. | C14H6O6Mg2 | Unit MW. | 318.80384 | ||
| Coordination Metal | Mg | Linkers | 2,5-Dihydroxy-[1, 1'-biphenyl ]-4, 4'-dicarboxylic acid (CAS: 13987-45-6) | ||
| Aperture |
2.2 nm |
Pore volume | 1.4 cm3/g | ||
| Surface Area | BET Specific surface >2500 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | Pale Yellow Powders |  |
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| Particle Size | 500nm-1um rod-like particles | |||
Stability
1) Mg2(dobpdc) is stable in air for weeks, but decomposed gradually in wet and hot conditions.
2) Thermal stability, thermal decomposition temperature above 350 ° C, though it will continuously lost weight from 150-300° C.
2) Thermal stability, thermal decomposition temperature above 350 ° C, though it will continuously lost weight from 150-300° C.
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for >12 hours at 250 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (e.g. carbon dioxide & CH4) and pollutant air adsorption
2) Mg2DOBPDC is instable in acqueous solutions, thus it could be used for drug adsorption and release
2) Mg2DOBPDC is instable in acqueous solutions, thus it could be used for drug adsorption and release
Characterizations
References
1) McDonald, Thomas M.; Lee, Woo Ram; Mason, Jarad A.; Wiers, Brian M.; Hong, Chang Seop; Long, Jeffrey R.; Journal of the American Chemical Society 2012, 134(16), 7056-7065, DOI: 10.1021/ja300034j ; Capture of Carbon Dioxide from Air and Flue Gas in the Alkylamine-Appended Metal–Organic Framework mmen-Mg2(dobpdc)
2）Lin, Li-Chiang; Kim, Jihan; Kong, Xueqian; Scott, Eric; McDonald, Thomas M.; Long, Jeffrey R.; Reimer, Jeffrey A.; Smit, Berend; Angew. Chem., Int. Ed. 2013, 52(16), 4410-4413, DOI:10.1002/anie.201300446 ; Understanding CO2 Dynamics in Metal-Organic Frameworks with Open Metal Sites
3) McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian; Bloch, Eric D.; Gygi, David; Dani, Alessandro; Crocella, Valentina; Giordanino, Filippo; Odoh, Samuel O.; Drisdell, Walter S.; Vlaisavljevich, Bess; Dzubak, Allison L.; Poloni, Roberta; Schnell, Sondre K.; Planas, Nora; Lee, Kyuho; Pascal, Tod; Wan, Liwen F.; Prendergast, David; Neaton, Jeffrey B.; Smit, Berend; Kortright, Jeffrey B.; Gagliardi, Laura; Bordiga, Silvia; Reimer, Jeffrey A.; Long, Jeffrey R.; Nature 2015, 519(7543), 303-308, DOI:10.1038/nature14327 ; Cooperative insertion of CO2 in diamine-appended metal-organic frameworks
4) Park, Jinkyoung; Park, Jeoung Ryul; Choe, Jong Hyeak; Kim, Saemi; Kang, Minjung; Kang, Dong Won; Kim, Jee Yeon; Jeong, Yong Won; Hong, Chang Seop; ACS Applied Materials & Interfaces 2020, 12(45), 50534-50540, DOI: 10.1021/acsami.0c16224 ; Metal-organic framework adsorbent for practical capture of trace carbon dioxide
