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1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with [1,1'-biphenyl]-4,4'-diamine

1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with [1,1'-biphenyl]-4,4'-diamine

CAS NO.:1428767-92-3Formula:C9H6O6.C12H12N2Weight: 394.37742
ProductTpBD COF
Synonyms1,3,5-Benzenetricarboxaldehyde, 2,4,6-trihydroxy-, polymer with [1,1'-biphenyl]-4,4'-diamine
CAS:1428767-92-3
Basic Information
Unit MF. C9H6O6.C12H12N2 Unit MW. 394.37742
Linkers

2,4,6-trihydroxy-1,3,5-benzenetricarbaldehyde (CAS:34374-88-4); 

benzidine (CAS: 92-87-5)

Aperture 1.0−1.7nm Pore volume  
Surface Area BET Specific surface 537 m2/g 
Analog Structure  
Product Property
Appearance

 

 
Particle Size  
Stability
1) It exhibits significant stability in boiling water, 9 N HCl, and 3 N NaOH;
Preservation
1) Dry and sealed under normal temperature or low temperature conditions;
2)Activate under high vacuum conditions at 170 ° C for 12 hours before use
Other Features
Fluorescence: NA
Applications
1) Due to its high crystallinity, good porosity, and excellent stability, it may have potential applications in gas storage, separation, catalysis, sensors, energy storage, and other fields;
2) The stability in water, acid, and alkali makes it potentially applicable in the fields of chemistry and environmental engineering;
Characterizations
XRD
 XRD-TpBD
SEM
 SEM--TpBD-COF-CS018582-3
BET
BET-TpBD-COF-CS018582-3
FTIR
FTIR-TpBD-COF-CS018582-3
References
 
1)Bishnu P. Biswal†Suman Chandra†Sharath Kandambeth†Binit Lukose‡Thomas Heine‡Rahul Banerjee*; J. Am. Chem. Soc. 2013, 135, 14, 5328–5331; DOI:10.1021/ja4017842; Mechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks【文献解读】;
2)Haijuan Tao, Jiale Liu, Weikang Guo, Qin Shuai & Lijin Huang; J. Anal. Test. 2024; DOI:10.1007/s41664-024-00330-1; Hydrophilic Chitosan/Covalent Organic Framework Composites for Efficient Solid-Phase Microextraction of Polar Phenolic Compounds Prior to Gas Chromatography: Mass Spectrometry Analysis;【文献解读】;
3) Haonan Qu, Defu An, Guang Li, Weiwei Xu, Cuiguang Ma, Haifan Zhang, Ehsan Bahojb Noruzi, Jing Cheng, Chuan Zhou,* Govindasami Periyasami,* and Haibing Li*; ACS Appl. Mater. Interfaces 2024, 16, 45, 62925–62933; DOI:10.1021/acsami.4c12738; Covalent Organic Framework Packed Nanoporous Membrane for Continuous Removal of Bisphenol A from Agricultural Irrigation Wastewater;