Product: PCN-222(Fe)
Synonyms: MOF-545(Fe)
CAS：1403461-06-2
Basic Information
| Unit MF. | C96H48N8O32Cl2Fe2Zr6 | Unit MW. | 2555.38 | ||
| Coordination Metal | Zr | Linkers | H2TCPP-(Fe) (CAS: 55266-17-6) | ||
| Pore Size | 3.7nm; 1.3 nm | Pore volume | 1.5 cm3/g | ||
| Surface Area | BET Specific surface >2000 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Dark Purple Powder | |||
| Particle Size | 2um*10um rodlike particles | |||
Stability
1) PCN-222(Fe) is stable in air, stable in aqueous and acidic conditions(stable in PH 1-11)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) PCN-222 has rigid channel framework, which is good carrier of catalyst and poentail material for gas and pollutant adorption.
2) With a pore size up to 3.7nm, PCN-222 is a pontential material for adsorption of drug molecular and enzyme/peptide
3) PCN-222(Fe) is able to convert O2 to singlet oxygen under light condition. It could be used as photocatalyst in organic reaction or as biosensors.
Characterizations
References
1) D. Feng, Z.-Y. Gu, J.-R. Li, H.-L. Jiang, Z. Wei, and H.-C. Zhou, Angew. Chem. 2012, 124, 10453-10456, DOI: 10.1002/ange.201204475 ; Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts
2) W. Morris, B. Volosskiy, S. Demir, F. Gándara, P. L. McGrier, H. Furukawa, D. Cascio, J. F. Stoddart, O. M. Yaghi, Inorg. Chem. 2012, 51, 6443-6445, DOI: 10.1021/ic300825s ; Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks；
3）Long Jiao, Gang Wan, Rui Zhang, Hua Zhou, Shu-Hong Yu, Hai-Long Jiang*; Angew Chem Int Ed, 2018, 57, 8525-8529; DOI：10.1002/anie.201803262; From Metal–Organic Frameworks to Single‐Atom Fe Implanted N‐doped Porous Carbons: Efficient Oxygen Reduction in Both Alkaline and Acidic Media；
4) Long Jiao, Weijie Yang, Gang Wan, Rui Zhang, Xusheng Zheng, Hua Zhou, Shu-Hong Yu, Hai-Long Jiang*; Angewandte Chemie International Edition, 2020, 59, 20589–20595; DOI：10.1002/anie.202008787; Single-Atom Electrocatalysts from Multivariate Metal–Organic Frameworks for Highly Selective Reduction of CO₂ at Low Pressures；
5) Rui Zhang, Long Jiao, Weijie Yang, Gang Wan, Hai-Long Jiang*; Journal of Materials Chemistry A, 2019, 7, 26371–26377; DOI：10.1039/c9ta10206j; Single-atom catalysts templated by metal–organic frameworks for electrochemical nitrogen reduction;
