Product: Al-PMOF
Synonyms: Al-TCPP
CAS：1654774-69-2 / 1402928-31-7
Basic Information
| Unit MF. | C48H26N4O10Al2 | Unit MW. | 872.70384 | ||
| Coordination Metal | Al | Linkers | H2TCPP (CAS: 14609-54-2) | ||
| Pore Size | 1.1nm; 0.6 nm | Pore volume | Micropore volume 0.6 cm3/g | ||
| Surface Area | BET Specific surface 1000-1400 m2/g | ||||
| Analog Structure |   |
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Product Property
| Appearance | Dark Purple Powder |  |
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| Particle Size | 300-500nm cubic nanoparticles | |||
Stability
1) PCN-222 is stable in air, stable in aqueous and acidic conditions(stable in PH 1-11)
2）High thermal stability, thermal decomposition temperature above 400 ° C
2）High thermal stability, thermal decomposition temperature above 400 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
Other Features
Fluorescence: λex=413nm, λem=643nm
Applications
1) Al-PMOF has rigid channel framework, which is good carrier of catalyst and poentail material for gas and pollutant adorption.
2) Al-PMOF(H or M) is able to convert O2 to singlet oxygen under light condition. It could be used as photocatalyst in organic reaction or as biosensors.
Characterizations
References
1) Fateeva, Alexandra; Chater, Philip A.; Ireland, Christopher P.; Tahir, Asif A.; Khimyak, Yaroslav Z.; Wiper, Paul V.; Darwent, James R.; Rosseinsky, Matthew J.; Angew. Chem., Int. Ed. 2012, 51(30), 7440-7444, DOI: 10.1002/anie.201202471 ; A Water-Stable Porphyrin-Based Metal-Organic Framework Active for Visible-Light Photocatalysis
2) Sadeghi, Nasrin; Sharifnia, Shahram; Do, Trong-On; J. Mater. Chem. A, 2018,6, 18031-18035, DOI: 10.1039/C8TA07158F ; Enhanced CO2 photoreduction by a graphene–porphyrin metal–organic framework under visible light irradiation
