Product Name:[1,1':4',1''-Terphenyl]-4,4''-dicarboxylic acid, 2',3',5',6'-tetramethyl-
Synonymous:TPDC-4CH3 ; H2TTTP;2',3',5',6'-Tetramethyl[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid
CAS:1394899-62-7
3) Klet, Rachel C.; Liu, Yangyang; Wang, Timothy C.; Hupp, Joseph T.; Farha, Omar K.; J. Mater. Chem. C 2016, 4(4), 1479-1485, DOI: 10.1039/C5TA07687K ; Evaluation of Bronsted acidity and proton topology in Zr- and Hf-based metal-organic frameworks using potentiometric acid-base titration
4) Pang, Jiandong; Yuan, Shuai; Qin, Junsheng; Wu, Mingyan; Lollar, Christina T.; Li, Jialuo; Huang, Ning; Li, Bao; Zhang, Peng; Zhou, Hong-Cai; J. Am. Chem. Soc. 2018, 140(39), 12328-12332, DOI: 10.1021/jacs.8b07411 ; Enhancing Pore-Environment Complexity Using a Trapezoidal Linker: Toward Stepwise Assembly of Multivariate Quinary Metal-Organic Frameworks
Synonymous:TPDC-4CH3 ; H2TTTP;2',3',5',6'-Tetramethyl[1,1':4',1''-terphenyl]-4,4''-dicarboxylic acid
CAS:1394899-62-7
Basic Info
M.F. | C24H22O4 | M.W. | 374.42908 | ||
Appearance | ![]() |
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:UIO-68-4Me / PCN-57 (Zr, Hf) [r1,r3] ; PCN-72 [r2];
Characterization
Reference
1) Jiang, Hai-Long; Feng, Dawei; Liu, Tian-Fu; Li, Jian-Rong; Zhou, Hong-Cai; J. Am. Chem. Soc. 2012, 134(36), 14690-14693, DOI: 10.1021/ja3063919 ; Pore Surface Engineering with Controlled Loadings of Functional Groups via Click Chemistry in Highly Stable Metal-Organic Frameworks
2) Liu, Yangyang; Chen, Ying-Pin; Liu, Tian-Fu; Yakovenko, Andrey A.; Raiff, Aaron M.; Zhou, Hong-Cai; CrystEngComm 2013, 15(45), 9688-9693, CrystEngComm, 2013,15, 9688-9693, Selective gas adsorption and unique phase transition properties in a stable magnesium metal-organic framework constructed from infinite metal chains5) Dascalu, Ioan-Andrei; Shova, Sergiu; Dumitrescu, Dan Gheorghe; Roman, Gheorghe; Bratanovici, Bogdan-Ionel; Ardeleanu, Rodinel; Lozan, Vasile; Polyhedron 2019, 170, 463-470, DOI: 10.1016/j.poly.2019.05.066 ; Coordination polymers of Cu(II), Co(II) and Cd(II) based on a tetramethyl-substituted terphenyldicarboxylic acid