Product: COF-366
Synonyms: H2P-DHPh;1,4-Benzenedicarboxaldehyde, polymer with 4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis[benzenamine]
CAS: 1381930-10-4
Basic Information
| Unit MF. | C44H34N8.C8H6O2 | Unit MW. | 808.93 | ||
| Coordination Metal | None | Linkers |
1) 1,4-Benzenedicarboxaldehyde; 2) 4,4′,4′′,4′′′-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis[benzenamine] |
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| Pore Size | 2.5 nm | Pore Volume | 0.78 cm3/g | ||
| Surface Area | 1094 m2/g | ||||
Product Property
| Appearance | Green powder | |||
| Particle Size | Uniform particles, ~500 nm | |||
Stability
1) Stable in dry air and insoluble in common organic solvents
2) Thermal decomposition temperature > 400°C
2) Thermal decomposition temperature > 400°C
Preservation
1) Keep in dry and cool condition
2) Activate by heating at room temperature in a vacuum oven for 3 hours before use
Other Features
Fluorescence: NA
Applications
1) Efficient gas adsorption and separation (e.g., H2, CO2)
2) Photocatalytic water splitting for hydrogen production
3) Organic optoelectronic materials
2) Photocatalytic water splitting for hydrogen production
3) Organic optoelectronic materials
Characterizations
References
1) Yaghi, Omar M.; Wan, Shun; Doonan, Christian J.; Wang, Bo; Deng, Hexiang; Journal of the American Chemical Society 2012, 134(37), 15360-15363, DOI: 10.1021/ja305587p ; Conductive Open Frameworks
2) Chen, Xiong; Addicoat, Matthew; Jin, Enquan; Zhai, Lipeng; Xu, Hong; Huang, Ning; Guo, Zhaoqi; Liu, Lili; Irle, Stephan; Jiang, Donglin; Journal of the American Chemical Society 2015, 137(10), 3241-3247, DOI: 10.1021/ja509602c ; Locking Covalent Organic Frameworks with Hydrogen Bonds: General and Remarkable Effects on Crystalline Structure, Physical Properties, and Photochemical Activity
