Product: Cu(BPZ)
Synonyms: [Cu(BPZ)]·MeCN
CAS：NA
Basic Information
| Unit MF. | C8H7CuN5 | Unit MW. | 236.72 | ||
| Coordination Metal | Cu | Linkers |
4,4'-Bi-1H-pyrazole（H2BPZ） |
||
| Pore Size | 1D rhombic channels along b axis (specific size not mentioned) | Pore volume | |||
| Surface Area | BET : ~300 m²/g | ||||
| Analog Structure | |||||
Product Property
| Appearance | Brown powders | NA | ||
| Particle Size | NA | |||
Stability
1) Thermal stability: Thermal decomposition temperature at about 350 °C.
2) Structural stability: Within the range of 30 - 210 °C, the material does not collapse due to solvent loss after undergoing multiple heating - cooling cycles. Moreover, its rhombohedral channels exhibit a certain degree of flexibility with temperature variations.
2) Structural stability: Within the range of 30 - 210 °C, the material does not collapse due to solvent loss after undergoing multiple heating - cooling cycles. Moreover, its rhombohedral channels exhibit a certain degree of flexibility with temperature variations.
Preservation
1) Keep in a dry and sealed condition.
2) Activation method: Before gas adsorption experiments, degas at 200 °C under dynamic vacuum (about 10⁻⁵ bar) until a constant weight is achieved.
2) Activation method: Before gas adsorption experiments, degas at 200 °C under dynamic vacuum (about 10⁻⁵ bar) until a constant weight is achieved.
Other Features
NA
Applications
1) Cu(BPZ) has the potential for selectively capturing small molecules and achieving efficient separation of gas mixtures.
2) The rhombohedral channels of CuBPZ exhibit a certain degree of flexibility, which can be utilized in the design of specialized sensors and adsorbent materials..
2) The rhombohedral channels of CuBPZ exhibit a certain degree of flexibility, which can be utilized in the design of specialized sensors and adsorbent materials..
Characterizations
References
1) Pettinari, Claudio, Aurel Tabacaru, Ishtvan Boldog, et al. Novel Coordination Frameworks Incorporating the 4,4′-Bipyrazolyl Ditopic Ligand. Inorganic Chemistry, 2012, 51(10): 5235 - 5245. DOI: 10.1021/ic3001416
