Product: Zn(BPZ)
Synonyms: NA
CAS: NA
Basic Information
| Unit MF. | C6H4N4Zn | Unit MW. | 197.5 | ||
| Coordination Metal | Zn | Linkers |
4,4′-bipyrazole |
||
| Pore Size | 1D square channels of ; 6.8 - 8.6 Å | Pore volume | 0.60 | ||
| Surface Area | BET> 800m2/g | ||||
| Analog Structure | NA | ||||
Product Property
| Appearance | White Powders | |||
| Particle Size | NA | |||
Stability
1) Stable in solutions with pH 3 - 13, water, and an environment with 50% relative humidity for 1 week, maintaining crystallinity and structural integrity.
2) High thermal stability, with a thermal decomposition temperature of approximately 420°C.
2) High thermal stability, with a thermal decomposition temperature of approximately 420°C.
Preservation
1) Keep in dry and sealed condition
2) Activate by degassing under dynamic vacuum (approx. ) at 200°C until a constant weight is achieved.
Other Features
NA
Applications
1) Separation of gas mixtures.
2) Selective capture of small molecules or ions (e.g. SiF6).
2) Selective capture of small molecules or ions (e.g. SiF6).
Characterizations
References
1) Pettinari, Claudio; Tabacaru, Aurel; Boldog, Ishtvan; Domasevitch, Konstantin V.; Galli, Simona; Masciocchi, Norberto. Inorg. Chem. 2012, 51, 5235 - 5245, DOI: 10.1021/ic3001416 ; Novel Coordination Frameworks Incorporating the 4,4′-Bipyrazolyl Ditopic Ligand
2) Fan, Qichen; Yao, Jinze; Zhao, Siyao; Wu, Xingbei; Huang, Jiajin; Luo, Haoyuan; Xia, Qibin. Small 2025, 2409215, DOI: 10.1002/smll.202409215 ; Construction of Multiple Nonpolar Nano - Traps by Highly Stable Pyrazole - Based MOFs for Recovery
2) Fan, Qichen; Yao, Jinze; Zhao, Siyao; Wu, Xingbei; Huang, Jiajin; Luo, Haoyuan; Xia, Qibin. Small 2025, 2409215, DOI: 10.1002/smll.202409215 ; Construction of Multiple Nonpolar Nano - Traps by Highly Stable Pyrazole - Based MOFs for Recovery
