Product: DUT-8(Ni)
Synonyms: Ni2(ndc)2dabco (ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo[2.2.2]octane)
CAS: 1254181-27-5
Basic Information
| Unit MF. | C30H24N2Ni2O8 | Unit MW. | 657.91 | ||
| Coordination Metal | Ni | Linkers |
2,6-naphthalenedicarboxylate (ndc) 1,4-diazabicyclo[2.2.2]octane (dabco) |
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| Pore Size | ~8.7 Å | Pore Volume | 0.97 cm³/g | ||
| Surface Area | 2635 m²/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Green powders (open pore phase), dark yellow powders (closed pore phase) | |||
| Particle Size | Size distribution is broad, small crystals less than 500 nm, large crystals up to over 100 µm | |||
Stability
1) It has a certain stability in specific solvent systems.
2) Thermal stability: Decomposition begins at 340 ° C-380 ° C.
Preservation
1) Keep in dry and cool conditions.
2) Activate by heating at 393 K under vacuum for 4 hours before use.
2) Activate by heating at 393 K under vacuum for 4 hours before use.
Other Features
Fluorescence: NA
Applications
1) Gas adsorption and separation, such as nitrogen, argon, etc.
2) Gas storage, utilizing its "gate-opening" characteristics for reversible gas adsorption and release.
3) Gas sensing, based on its adsorption response Characterizations
2) Gas storage, utilizing its "gate-opening" characteristics for reversible gas adsorption and release.
3) Gas sensing, based on its adsorption response Characterizations
Characterizations
References
1) Kavoosi, Negar; Bon, Volodymyr; Senkovska, Irena; Krause, Simon; Atzori, Cesare; Bonino, Francesca; Pallmann, Julia; Paasch, Silvia; Brunner, Eike; Kaskel, Stefan; Dalton Transactions (2017), 46(15), 4685-4695, DOI: 10.1039/c7dt00015d; Tailoring adsorption induced phase transitions in the pillared-layer type metal-organic framework DUT-8(Ni)
