Product Name：2-amino-[1,1'-biphenyl]-4,4'-dicarboxylic acid
Synonymous：H2BPDC-NH2; H2amineBPDC
CAS：1240557-01-0
Synonymous：H2BPDC-NH2; H2amineBPDC
CAS：1240557-01-0
Basic Info
| M.F. | C14H11NO4 | M.W. | 257.24144 | ||
| Appearance |  |
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Properties
1) 1240557-01-0 is soluble in DMF and DMSO
2) 2-8 ℃ sealed storage
2) 2-8 ℃ sealed storage
Appications
1) It could be used as monomer linker for MOF synthesis: UiO-67-m-NH2 [r4,r5]; DUT-5 amine [r2]; N3/NH2-bMOF-100 [r3]
Characterization
Reference
1) R. K. Deshpande, J. L. Minnaar, S. G. Telfer, Angew. Chem. Int. Ed. 2010, 49, 4598– 4602, DOI:10.1002/anie.200905960 ; Thermolabile Groups in Metal–Organic Frameworks: Suppression of Network Interpenetration, Post‐Synthetic Cavity Expansion, and Protection of Reactive Functional Groups
2) M. Gotthardt, S. Grosjean, T. Brunner, J. Kotzel, A. Gänzler, S. Wolf, S. Bräse, W. Kleist, Dalton Trans., 2015,44, 16802-16809 DOI: 10.1039/C5DT02276B ; Synthesis and post-synthetic modification of amine-, alkyne-, azide- and nitro-functionalized metal–organic frameworks based on DUT-5
3) C. Liu, T. Luo, E. Feura, C. Zhang, N. Rosi, J. Am. Chem. Soc. 2015, 137(33), 10508-10511, DOI:10.1021/jacs.5b06780 ; Orthogonal Ternary Functionalization of a Mesoporous Metal–Organic Framework via Sequential Postsynthetic Ligand Exchange
4) Katz, M.; Brown, Z.; Colon, Y.; Siu, P.; Scheidt, K.; Snurr, R.; Hupp, J.; Farha, O.; Chem. Commun., 2013,49, 9449-9451, DOI: 10.1039/C3CC46105J ; A facile synthesis of UiO-66, UiO-67 and their derivatives
5) Peterson, G.W.; Moon, S.; Wagner, G.; Hall, M.; De Coste, J.; Hupp, J.; Farha, O.; Inorg. Chem. 2015, 54, 20, 9684-9686, DOI: 10.1021/acs.inorgchem.5b01867 ; Tailoring the Pore Size and Functionality of UiO-Type Metal–Organic Frameworks for Optimal Nerve Agent Destruction
