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4'-(2h-tetrazol-5-yl)-[1,1'-biphenyl]-3,5-dicarboxylic acid

4'-(2h-tetrazol-5-yl)-[1,1'-biphenyl]-3,5-dicarboxylic acid

CAS NO.:1159595-96-6Formula:C15H10N4O4Weight: 310.2643
Product Name:5-​(4-​(Tetrazol-​5-​yl)​phenyl)​isophthalic acid
Synonymous:H3TZBPDC ; TBDA ; H3tzpa;4'-​(2H-​Tetrazol-​5-​yl)​[1,​1'-​biphenyl]​-​3,​5-​dicarboxylic acid; 4'-​(1H-​Tetrazol-​5-​yl)​(1,​1'-​biphenyl)​-​3,​5-​dicarboxylic acid;
CAS:1159595-96-6
Basic Info
M.F. C15H10N4O4 M.W. 310.2643
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Zn2(TZBPDC)​(μ3-​OH)​(H2O)​2] [r2]; Zn-​TBDA [r4]; [Co2(tzpa)​(OH)​(H2O)​2] [r5]
Characterization
HNMR
NA
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Eubank, Jarrod F.; Nouar, Farid; Luebke, Ryan; Cairns, Amy J.; Wojtas, Lukasz; Alkordi, Mohamed; Bousquet, Till; Hight, Matthew R.; Eckert, Juergen; Embs, Jan P.; Georgiev, Peter A.; Eddaoudi, Mohamed; Angew. Chem., Int. Ed. 2012, 51(40), 10099-10103, DOI: 10.1002/anie.201201202 ; On Demand: The Singular rht Net, an Ideal Blueprint for the Construction of a Metal-​Organic Framework (MOF) Platform
2) Hu, Yingli; Ding, Meili; Liu, Xiao-Qin; Sun, Lin-Bing; Jiang, Hai-Long; Chem. Commun. 2016, 52(33), 5734-5737, DOI: 10.1039/C6CC01597B ; Rational synthesis of an exceptionally stable Zn(II) metal-​organic framework for the highly selective and sensitive detection of picric acid
3) Wu, Lan-Lan; Zhao, Junfang; Wang, Hui; Wang, Jingyuan; CrystEngComm 2016, 18(23), 4268-4271, DOI: 10.1039/C5CE02444G ; A lanthanide(III) metal-​organic framework exhibiting ratiometric luminescent temperature sensing and tunable white light emission
4) Lin, Wenxin; Hu, Quan; Jiang, Ke; Cui, Yuanjing; Yang, Yu; Qian, Guodong; Microporous and Mesoporous Materials 2017, 249, 55-60, DOI: 10.1016/j.micromeso.2017.04.042 ; A porous Zn-​based metal-​organic framework for pH and temperature dual-​responsive controlled drug release

5) Wang, Hai-Hua; Hou, Lei; Li, Yong-Zhi; Jiang, Chen-Yu; Wang, Yao-Yu; Zhu, Zhonghua; ACS Applied Materials & Interfaces 2017, 9(21), 17969-17976, DOI: 10.1021/acsami.7b03835 ; Porous MOF with Highly Efficient Selectivity and Chemical Conversion for CO2