Product: COF-300
Synonyms: 1,4-Benzenedicarboxaldehyde, polymer with 4,4',4'',4'''-methanetetrayltetrakis[benzenamine]
CAS： 1133843-97-6
Basic Information
| Unit MF. | C12H18N4O4.C9H6O3 | Unit MW. | 444.44 | ||
| Linkers | Tetra(4-anilyl)methane （CAS: 60532-63-0）; Terephthalaldehyde (623-27-8) | ||||
| Pore Size | 0.8 nm | Pore volume | 0.8 cm3/g | ||
| Surface Area | BET > 1200m2/g |
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| Analog Structure |  |
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Product Property
| Appearance | Orange/Yellow Powders |  |
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| Particle Size | 500nm particles or aggregated nanoparticles | |||
Stability
1) COF-300 is stable in sealed condition for weeks, and stable in water and common organic solvent
2) Thermally stable, thermal decomposition temperature of COF-300 is above 450 ° C
2) Thermally stable, thermal decomposition temperature of COF-300 is above 450 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 10 hours at 120 degree in vacuum.
Other Features
Fluorescence: NA
Applications
1) Gas (such as CO2) and pollutant adsorption
2) With rigid 3D framework, COF-300 is a potential carrier of catalyst
2) With rigid 3D framework, COF-300 is a potential carrier of catalyst
Characterizations
References
1）Uribe-Romo, Fernando J.; Hunt, Joseph R.; Furukawa, Hiroyasu; Kloeck, Cornelius; O'Keeffe, Michael; Yaghi, Omar M.; J. Am. Chem. Soc. 2009, 131(13), 4570-4571, DOI: 10.1021/ja8096256 ; A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework；
2) Fischbach, Danyon M.; Rhoades, Grace; Espy, Charlie; Goldberg, Fallon; Smith, Brian J.; Chem. Commun. 2019, 55(25), 3594-3597, DOI: 10.1039/c8cc09571j ; Controlling the crystalline structure of imine-linked 3D covalent organic frameworks
3) Zhu, Dongyang; Zhang, Zhuqing; Alemany, Lawrence b.; Li, Yilin; Nnorom, Njideka; Barnes, Morgan; Khalil, Safiya; Rahman, Muhammad m.; Ajayan, Pulickel m.; Verduzco, Rafael; Chem. Mater. 2021, 33(9), 3405-3411, DOI: 10.1021/acs.chemmater.1c00737 ; Rapid, Ambient Temperature Synthesis of Imine Covalent Organic Frameworks Catalyzed by Transition-Metal Nitrates；
4） Xueying Kong, Zhongqi Wu, Maria Strømme, and Chao Xu*; J. Am. Chem. Soc. 2024, 146, 1, 742–751; DOI：10.1021/jacs.3c10691; Ambient Aqueous Synthesis of Imine-Linked Covalent Organic Frameworks (COFs) and Fabrication of Freestanding Cellulose Nanofiber@COF Nanopapers;
5) Yuxi Wu, Yuhong Tian,* Xinping He, Jiaxin Guo, Kaiya Yi, and Chunhai Yi*; Ind. Eng. Chem. Res. 2024, 63, 45, 19756–19766; DOI：10.1021/acs.iecr.4c02886; Preparation of Covalent Organic Framework/PDMS Mixed Matrix Membranes for Efficient Ethanol Recovery via Pervaporation;
