Product: UIO-68(Zr)
Synonyms: NA
CAS：1072413-85-4
Basic Information
| Unit MF. | C120H12O32Zr6 | Unit MW. | 2512.70408 | ||
| Coordination Metal | Zr | Linkers | 4-[4-(4-carboxyphenyl)phenyl]benzoic acid (CAS: 13653-84-4) | ||
| Aperture | 1.77nm | Pore volume | 1.8 cm3/g | ||
| Surface Area | BET surface area >3000 m2/g, | ||||
| Analog Structure |   |
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Product Property
| Appearance | White Powder |  |
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| Particle Size | 500nm-1um | |||
Stability
1) UIO-68 is stable in air. But not stable in aqueous conditions, totally destroyed after 24h soaked in aquoes solutions.
2) High thermal stability, thermal decomposition temperature above 500 ° C
2) High thermal stability, thermal decomposition temperature above 500 ° C
Preservation
1) Keep sealed in dry and cool condition
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
2) It is recommended to activate for 3 hours at 150 degree in vacuum.
Other Features
Fluorescence: λem=357nm， λex=438nm
Applications
1) With ultrahigh surface area, potential material for gas (such as carbon dioxide) and pollutant adsorption
2) UIO-68 has very rigid framework, which is good carrier of catalyst.
2) UIO-68 has very rigid framework, which is good carrier of catalyst.
Characterizations
References
1) J. H. Cavka, S. Jakobsen, U. Olsbye, N. Guillou, C. Lamberti, S. Bordiga, K. P. Lillerud, J. Am. Chem. Soc. 2008, 130, 13850-13851, DOI: 10.1021/ja8057953 ; A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
2) S. J. Garibaya, S. M. Cohen, Chem. Commun., 2010,46, 7700-7702, DOI: 10.1039/C0CC02990D ; Isoreticular synthesis and modification of frameworks with the UiO-66 topology
3) K. Manna, P. Ji, Z. Lin, F. Greene, A. Urban, Na. Thacker, W. Lin, Nat. Commun. 2016, 7, 12610, DOI: 10.1038/ncomms12610 ; Chemoselective single-site Earth-abundant metal catalysts at metal–organic framework nodes
