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2,5-diethoxy-1,4-benzenedicarboxylic acid

2,5-diethoxy-1,4-benzenedicarboxylic acid

CAS NO.:105338-33-8Formula:C12H14O6Weight: 254.23596
Product Name:2,​5-​Diethoxyterephthalic Acid
Synonymous:;2,​5-​Diethoxy-​1,​4-​benzenedicarboxylic acid;
CAS:105338-33-8
Basic Info
M.F. C12H14O6 M.W. 254.23596
Appearance  
Properties
1)   It is soluble in DMF and DMSO
2)   Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Zn2(Ethoxyl-​bdc)​2(dabco)​]​n [r2]; UiO-​66-​(OEt)​2 [r3]; MOF-5-C2 [r4]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Sotzing, Gregory A.; Reynolds, John R.; Katritzky, Alan R.; Soloducho, Jadwiga; Belyakov, Sergei; Musgrave, Richard; Macromolecules 1996, 29(5), 1679-1684, DOI: 10.1021/MA950999O ; Poly[bis(pyrrol-​2-​yl)​arylenes]​: Conducting Polymers from Low Oxidation Potential Monomers Based on Pyrrole via Electropolymerization
2) Henke, Sebastian; Schneemann, Andreas; Wuetscher, Annika; Fischer, Roland A.; Journal of the American Chemical Society 2012, 134(22), 9464-9474, DOI: 10.1021/ja302991b ; Directing the Breathing Behavior of Pillared-​Layered Metal-​Organic Frameworks via a Systematic Library of Functionalized Linkers Bearing Flexible Substituents
3) Hu, Zhigang; Peng, Yongwu; Kang, Zixi; Qian, Yuhong; Zhao, Dan; Inorg. Chem. 2015, 54(10), 4862-4868, DOI: 10.1021/acs.inorgchem.5b00435 ; A Modulated Hydrothermal (MHT) Approach for the Facile Synthesis of UiO-​66-​Type MOFs
4) Pallach, Roman; Keupp, Julian; Terlinden, Kai; Frentzel-Beyme, Louis; Kloss, Marvin; Machalica, Andrea; Kotschy, Julia; Vasa, Suresh K.; Chater, Philip A.; Sternemann, Christian; Wharmby, Michael T.; Linser, Rasmus; Schmid, Rochus; Henke, Sebastian; Nat. Commun. 2021, 12, 4097, DOI: 10.1038/s41467-021-24188-4 ; Frustrated flexibility in metal-organic frameworks
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