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Home > Product Category > MOF Materials > MOFs by Metals > Zn-MOFs
CAS NO.:1033723-90-8Formula:C8H4O8Zn2Weight: 358.893

Product: MOF-74(Zn)
Synonyms: Zn-MOF-74 ; Zn-DOBDC; CPO-27(Zn); Zn2(dhtp)
CAS:1033723-90-8

Basic Information
Unit MF. C8H4O8Zn2 Unit MW. 358.89
Coordination  Metal Zn Linkers 2,5-Dihydroxyterephthalic acid (CAS: 610-92-4)
Aperture

1.2 nm

Pore volume 0.6 cm3/g
Surface Area BET Specific surface 600 m2/g,
Analog Structure      
Product Property
Appearance  Yellow Powder / Light Pink or brown Powders   
Particle Size 3-5um irregular bulk particles
Stability
1) MOF-74(Zn) is stable in air for weeks, but decomposed gradually in wet and hot conditions. It is instable in acqueous solutions.
2)Thermal stability, thermal decomposition temperature above 300 ° C
Preservation
1) Keep sealed in dry and cool condition 
2) It is recommended to activate for >6 hours at 150 degree in vacuum.
Other Features
Fluorescence:NA
Applications
1) Gas (e.g. carbon dioxide & CH4) and pollutant air adsorption
2) MOF-74 is instable in acqueous solutions, thus it could be used for drug adsorption and release
Characterizations
XRD
XRD-MOF-74(Zn)
BET
BET-MOF-74-Ni
SEM
SEM-MOF-74(Zn)
FTIR
NA
References
1)J.K. Nathaniel, L. Rosi, Eddaoudi Mohamed, Banglin Chen, Michael O'Keeffe, Omar M. Yaghi, J. Am. Chem. Soc. 2005, 127, 1504–1518, DOI: 10.1021/ja045123o ; Rod packings and Metal−Organic frameworks constructed from rod-shaped secondary building units;
2)David Britt, David Tranchemontagne, Omar M. Yaghi; PNAS, 2008, 105, 33; DOI:10.1073/pnas.0804900105; Metal-organic frameworks with high capacity and selectivity for harmful gases;