Product: ZIF-69
Synonyms: NA
CAS:1018477-10-5
Basic Information
| Unit MF. | C10H6N5O2ClZn | Unit MW. | 329.03 | ||
| Coordination Metal | Zn | Linkers |
2-nitroimidazole (nIm) |
||
| Pore Size | 7.8 Å | Pore Volume | Not mentioned | ||
| Surface Area | 950 m²/g | ||||
| Analog Structure | / | ||||
Product Property
| Appearance | Yellow Crystals | |||
| Particle Size | NA | |||
Stability
1) Stable in boiling water, methanol, and benzene for up to 7 days
2) Stable after heating at 300°C
3) TGA shows weight loss starting around 371°C
2) Stable after heating at 300°C
3) TGA shows weight loss starting around 371°C
Preservation
1) Keep in dry and cool condition
2) Activate by heating at room temperature in a vacuum oven for 3 hours
Other Features
Fluorescence: NA
Applications
1) Gas adsorption and separation, suitable for natural gas purification and landfill gas separation
2) Energy storage, can be used as electrode material for supercapacitors
3) Catalysis, applicable for CO2 reduction reactions
2) Energy storage, can be used as electrode material for supercapacitors
3) Catalysis, applicable for CO2 reduction reactions
Characterizations
References
1) Banerjee, Rahul; Furukawa, Hiroyasu; Britt, David; Knobler, Carolyn; O'Keeffe, Michael; Yaghi, Omar M.; J. Am. Chem. Soc. 2009, 131, 3875–3877, DOI: 10.1021/ja809459e; Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
2) Palaniselvam, Thangavelu; Biswal, Bishnu P.; Banerjee, Rahul; Kurungot, Sreekumar; Chem. Eur. J. 2013, 19, 9335 – 9342, DOI: 10.1002/chem.201300145; Zeolitic Imidazolate Framework (ZIF)-Derived, Hollow-Core, Nitrogen-Doped Carbon Nanostructures for Oxygen-Reduction Reactions in PEFCs


