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ZIF-69

ZIF-69

CAS NO.:1018477-10-5Formula:C10H6N5O2ClZnWeight: 329.03

Product: ZIF-69
Synonyms: NA
CAS:1018477-10-5

Basic Information
Unit MF. C10H6N5O2ClZn Unit MW. 329.03
Coordination Metal Zn Linkers

2-nitroimidazole (nIm)
5-chlorobenzimidazole (cbIm)

Pore Size 7.8 Å Pore Volume Not mentioned
Surface Area 950 m²/g
Analog Structure /
Product Property
Appearance Yellow Crystals  
Particle Size NA
Stability
1) Stable in boiling water, methanol, and benzene for up to 7 days
2) Stable after heating at 300°C
3) TGA shows weight loss starting around 371°C
Preservation
1) Keep in dry and cool condition
2) Activate by heating at room temperature in a vacuum oven for 3 hours
Other Features
Fluorescence: NA
Applications
1) Gas adsorption and separation, suitable for natural gas purification and landfill gas separation
2) Energy storage, can be used as electrode material for supercapacitors
3) Catalysis, applicable for CO2 reduction reactions
Characterizations
XRD
NA
SEM
NA
BET
NA
FTIR
NA
References
1) Banerjee, Rahul; Furukawa, Hiroyasu; Britt, David; Knobler, Carolyn; O'Keeffe, Michael; Yaghi, Omar M.; J. Am. Chem. Soc. 2009, 131, 3875–3877, DOI: 10.1021/ja809459e; Control of Pore Size and Functionality in Isoreticular Zeolitic Imidazolate Frameworks and their Carbon Dioxide Selective Capture Properties
2) Palaniselvam, Thangavelu; Biswal, Bishnu P.; Banerjee, Rahul; Kurungot, Sreekumar; Chem. Eur. J. 2013, 19, 9335 – 9342, DOI: 10.1002/chem.201300145; Zeolitic Imidazolate Framework (ZIF)-Derived, Hollow-Core, Nitrogen-Doped Carbon Nanostructures for Oxygen-Reduction Reactions in PEFCs