Product Name：1,4-Bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
Synonymous：bimx ; BTIB ; p-tmbix ; p-bitmb;1,1'-[(2,3,5,6-Tetramethyl-1,4-phenylene)bis(methylene)]bis[1H-imidazole]
CAS：1012075-54-5
3) Kose Yaman, Pelin; Arici, Mursel; Erer, Hakan; Yesilel, Okan Zafer; J. Mole. Struct. 2021, 1229, 129499, DOI: 10.1016/j.molstruc.2020.129499 ; The Effect of Metal Salts on The Structures of 2,2-Dimethylglutarate Complexes with a Flexible 1,4-bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene
4) Zhang, Yan; Luo, Wenping; Liu, Dongju; Xu, Yan; Li, Shun-Li; Li, Jingfu; Wu, Yong; Zhou, Yaoming; Fang, Min; Liu, Hong-Ke; Inorg. Chimi. Acta 2014, 409(PB), 512-517, DOI: 10.1016/j.ica.2013.09.043 ; Structures and photoluminescence properties of two cadmium(II) coordination polymers synthesized by flexible and rigid ligands
Synonymous：bimx ; BTIB ; p-tmbix ; p-bitmb;1,1'-[(2,3,5,6-Tetramethyl-1,4-phenylene)bis(methylene)]bis[1H-imidazole]
CAS：1012075-54-5
Basic Info
| M.F. | C18H22N4 | M.W. | 294.39408 | ||
| Appearance | |||||
Properties
1) It is soluble in DMF and DMSO
2) Sealed at room temperature
2) Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:[Zn(bdc)(bimx)] [r1]; [Cu(CO3)(btib)] [r2]; [Cd(BDC)(m-bitmb)(H2O)] [r4]
Characterization
Reference
1) Schaate, Andreas; Klingelhoefer, Stefan; Behrens, Peter; Wiebcke, Michael; Cryst. Growth & Des. 2008, 8(9), 3200-3205, DOI: 10.1021/cg701041k ; Two Zinc(II) Coordination Polymers Constructed with Rigid 1,4-Benzenedicarboxylate and Flexible 1,4-Bis(imidazol-1-ylmethyl)-2,3,5,6-tetramethylbenzene Linkers: From Interpenetrating Layers to Templated 3D Frameworks
2) Inoue, Tatsunari; Yamanishi, Katsunori; Kondo, Mitsuru; Inorg. Chem. 2013, 52(9), 4765-4767,DOI: 10.1021/ic400315g ; Solvent-Soluble Coordination Polymer That Reconstructs Cyclic Frameworks That Trap a Kinetically Labile [Cu(CO3)2]2- Unit