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4,4',4'',4'''-(1,9-dihydropyrene-1,3,6,8-tetrayl)tetrabenzoicacid

4,4',4'',4'''-(1,3,6,8-pyrenetetrayl)tetrakis-Benzoic acid

CAS NO.:933047-52-0Formula:C44H26O8Weight: 682.67244
Product Name:1,3,6,8-Tetra(4-​carboxylphenyl)​ pyrene
Synonymous:H4TBAPy; 1,​3,​6,​8-​tetrakis(p-​HOBz)​pyrene
CAS:933047-52-0
Basic Info
M.F.  C44H26O8 M.W.  682.7
Appearance  
Properties
1)  933047-52-0 is soluble in DMF and DMSO
2)  Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:NU-1000/901;  [Zn2(TBAPy)(H2O)2]
2) It could be used as monomer for HOF (Hydrogen-Bonded Organic Frameworks) synthesis: PFC-1(HOF-101) [r5]
Characterization
HNMR
 
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Sagara, Y.; Mutai, T.; Yoshikawa, I.; Araki, K.; J. Am. Chem. Soc., 2007, 129(6), 1520-1521, DOI:10.1021/ja0677362 ; Material Design for Piezochromic Luminescence:  Hydrogen-Bond-Directed Assemblies of a Pyrene Derivative 
2) Stylianou, K.; Heck, R.; Chong, S.; Bacsa, J.; Jones, J.; Khimyak, Y.; Bradshaw, .; Rosseinsky, M.; J. Am. Chem. Soc., 2010, 132(12), 4119-4130, DOI:10.1021/ja906041f ; A Guest-Responsive Fluorescent 3D Microporous Metal−Organic Framework Derived from a Long-Lifetime Pyrene Core 
3) J. E. Mondloch, W. Bury, D. Fairen-Jimenez, S. Kwon, E. J. DeMarco, M. H. Weston, A. A. Sarjeant, S. T. Nguyen, P. C. Stair, R. Q. Snurr, O. K. Farha and J. T. Hupp, J. Am. Chem. Soc., 2013, 135, 10294-10297, DOI:10.1021/ja4050828 ; Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework 
4) Li, R.; Li, M.; Zhou, X.; Li, D.; O'Keeffe, M.; Chem. Commun., 2014, 50(31), 4047-4049, DOI:10.1039/C3CC49684H
5) Yin, Q.; Zhao, P.; Sa, R.; Chen, G.; Lue, J.; Liu, T.; Cao, R.; Angew. Chem., Int. Ed. 2018, 57(26), 7691-7696, DOI:10.1002/anie.201800354
HNMR-933047-52-0-CS013472.pdf Download
HNMR-933047-52-0-CS013472.pdf Download
933047-52-0-CS014025-1-HNMR.pdf Download
933047-52-0-CS013567HNMR.pdf Download
933047-52-0-CS013814.pdf Download
933047-52-0-CS013813.pdf Download
933047-52-0-CS013515.pdf Download
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CS014025-1-HPLC.pdf Download