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5'-(4-Carboxyphenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylic acid

1,3,5-Tri(4-carboxyphenyl)benzene

CAS NO.:50446-44-1Formula:C27H18O6Weight: 438.42822
Product Name:1,3,5-Tri(4-carboxyphenyl)benzene
Synonymous:H3BTB;1,​3,​5-​benzenetrisbenzoic acid;  5'-(4-carboxyphenyl)-[1,1':3',1''-terphenyl]-4,4''-dicarboxylicacid
CAS:50446-44-1
Basic Info
M.F. C27H18O6 M.W. 438.43
Appearance
Properties
1) H3BTB is soluble in DMF and DMSO
2) H3BTB is stable in air.
Appications
1) 50446-44-1 could be used as monomer linker for MOF or HOF synthesis:MOF-177 [r3], MOF-205 [r4], MOF-519(Al) [r5]; MOF-777; MOF-14(Cu) [r1]/MOF-143; MOF-39(Zn) [r2] BIT-66(V) [r10 ];  PCN-134 [r7]; MIL-103/Ln-BTB [r9]; MIL-142/143 [r8]; UMCM-1
2) 50446-44-1 could be used as monomer for 2D polyamide and polyesters
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Chen, B.; Eddaoudi, M.; Hyde, S. T.; O'Keeffe, M.; Yaghi, O. M. Science 2001, 291(5506), 1021-1023, DOI:10.1126/science.1056598
2) Kim, J.; Chen, B.; Reineke, T.; Li, H.; Eddaoudi, M.; Moler, D.; O'Keeffe, M.; Yaghi, O.; J. Am. Chem. Soc. 2001, 123(34), 8239-8247, DOI:10.1021/ja010825o
3) Chae, H.; Siberio-Perez, D.; Kim, J.; Go, Y.; Eddaoudi, M.; Matzger, A.; O'Keeffe, M.; Yaghi, O.; Nature 2004, 427(6974), 523-527, DOI:10.1038/nature02311
4) PCT Int. Appl. (2011), WO 2011038208 A2 20110331
5) Gandara, F.; Furukawa, H.; Lee, S.; Yaghi, O.;  J. Am. Chem. Soc. 2014, 136(14), 5271-5274, DOI:10.1021/ja501606h
6) PCT Int. Appl. (2015), WO 2015127033 A1 20150827
7) Yuan, S.; Qin, J.; Zou, L.; Chen, Y.; Wang, X.; Zhang, Q.; Zhou, H.;  J. Am. Chem. Soc. 2016, 138(20), 6636-6642, DOI:10.1021/jacs.6b03263
8) Chevreau, H.; Devic, T.; Salles, F.; Maurin, G.; Stock, N.; Serre, C.; Angew. Chem., Int. Ed. 2013, 52(19), 5056-5060, DOI:10.1002/anie.201300057
9) Liu, Q.; Yang, J.; Guo, F.; Jin, L.; Sun, W.; Dal. Trans. 2016, 45(13), 5841-5847, DOI:10.1039/C5DT04944J
10) Ma, D.; Li, P.; Duan, X.; Li, J.; Shao, P.; Lang, Z.; Bao, L.; Zhang, Y.; Lin, Z.; Wang, B.; Angew. Chem., Int. Ed. 2020, 59(10), 3905-3909, DOI: 10.1002/anie.201914762
50446-44-1-CS007051.pdf Download
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50446-44-1-CS007051-HPLC.PDF Download
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