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meso-Tetra(4-carboxyphenyl)porphine

meso-Tetra(4-carboxyphenyl)porphine

CAS NO.:14609-54-2Formula:C48H30N4O8Weight: 790.7738
Product Name:4,4',4'',4'''-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis-Benzoicacid
Synonymous:meso-Tetra(4-carboxyphenyl)porphine;H2TCPP
CAS:14609-54-2
Basic Info
M.F.  C48H30N4O8 M.W. 790.77 
Appearance  
Properties
1)  14609-54-2 soluble in DCM, DMF, DMSO, etc.
2)  Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis: PCN-222 [r2]; PCN-223; PCN-224 [r3]/225 [r5]; PCN-600; MOF-525/535/545 [r4]; Al-​PMOF [r6]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Niedercorn, F.; Ledon, H.; Tkatchenko, I.; New Journal of Chemistry 1988, 12(11-12), 897-906. 
2) Feng, D. ; Gu, Z.-Y. ; Li, J.-R.; Jiang, H.-L.; Wei, Z.; Zhou, H.-C.;  Angew. Chem., Int. Ed. 2012, 124, 10453-10456, DOI:10.1002/anie.201204475 ; Zirconium‐Metalloporphyrin PCN‐222: Mesoporous Metal–Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts   
3) Feng, D.; Chung, W.; Wei, Z.; Gu, Z.; Jiang, H.; Chen, Y.; Darensbourg, D.; Zhou, H.; J. Am. Chem. Soc. 2013, 135(45), 17105-17110, DOI:10.1021/ja408084j ; Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination 
4) Morris, W.; Volosskiy, B.; Demir, S.; Gandara, F.; McGrier, P.; Furukawa, H.; Cascio, D.; Stoddart, J.; Yaghi, O.; Inorg. Chem. 2012, 51(12), 6443-6445, DOI:10.1021/ic300825s ; Synthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks 
5) Jiang, H.; Feng, D.; Wang, K.; Gu, Z.; Wei, Z.; Chen, Y.; Zhou, H.; J. Am. Chem. Soc. 2013, 135(37), 13934-13938, DOI:10.1021/ja406844r ; An Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence
6) Fateeva, A.; Chater, .; Ireland, C.; Tahir, A.; Khimyak, Y.; Wiper, P.; Darwent, J.; Rosseinsky, M.; Angew. Chem., Int. Ed. 2012), 51(30), 7440-7444, DOI:10.1002/anie.201202471 ; A Water‐Stable Porphyrin‐Based Metal–Organic Framework Active for Visible‐Light Photocatalysis
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