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4',4''',4'''''-nitrilotris(([1,1'-biphenyl]-4-carboxylicacid))

4',4''',4'''''-nitrilotris(([1,1'-biphenyl]-4-carboxylic acid))

CAS NO.:1239602-35-7Formula:C39H27NO6Weight: 605.63478
Product Name:tris(4'-carboxybiphenyl)amine; tris((4-carboxyl)phenylduryl)amine
Synonymous:H3TCBPA; H3TPA; H3TBPA; H3BTCA
CAS:1239602-35-7
Basic Info
M.F.  C39H27NO6 M.W.  605.18
Appearance  
Properties
1)  1239602-35-7 is soluble in DMF and DMSO
2)  Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:SNU-77 [r1];  FIR-1 [r2]; DUT-63/64 [r5]; ZSTU-​3 [r4]etc.
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Park, H. J.; Lim, D. W.; Yang, W. S.; Oh, T. R.; Suh, M. P. Chem. - Eur. J. 2011, 17, 7251– 7260 DOI: 10.1002/chem.201003376 ; A Highly Porous Metal–Organic Framework: Structural Transformations of a Guest‐Free MOF Depending on Activation Method and Temperature   
2) He, Y. P.; Tan, Y. X.; Wang, F.; Zhang, J. Inorg. Chem. 2012, 51, 1995– 1997 DOI: 10.1021/ic202713e ; Microporous Zinc Tris[(4-carboxyl)phenylduryl]amine Framework with an Unusual Topological Net for Gas Storage and Separation 
3) Wang, Y.; Liu, Q.; Zhang, Q.; Peng, B.; Deng, H. Angew. Chem., Int. Ed. 2018, 57, 7120– 7125, DOI: 10.1002/anie.201803201 ; Molecular Vise Approach to Create Metal‐Binding Sites in MOFs and Detection of Biomarkers
4) Mueller, P.; Gruenker, R.; Bon, V.; Pfeffermann, M.; Senkovska, I.; Weiss, M.; Feng, X.; Kaskel, S.; CrystEngComm 2016, 18(42), 8164-8171, DOI: 10.1039/C6CE01513A
HNMR-1239602-35-7-CS004172.pdf Download
1239602-35-7-CS014103.pdf Download
LCMS-1239602-35-7-CS004172.pdf Download