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4,4',4''-nitrilotribenzoic acid

4,4',4''-nitrilotribenzoic acid

CAS NO.:118996-38-6Formula:C21H15NO6Weight: 377.3469
Product Name:4,4',4''-nitrilotribenzoic acid
Synonymous:H3TCA; H3NTB
CAS:118996-38-6
Basic Info
M.F.  C21H15NO6 M.W.  377.3469
Appearance  
Properties
1)  118996-38-6 is soluble in DMF and DMSO
2)  Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:MOF-150 [r1]; UMCM-4 [r2]; Zn4O(NTB)​2 [r3];  Zn-​PYI1/2 [r4]; ZSTU-​1 [r5]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Chae, H.; Kim, J.; Friedrichs, O.; O'Keeffe, M.; Yaghi, O.;  Angew. Chem., Int. Ed., 2003, 42 , 3907-3909, DOI: 10.1002/anie.200351546 ; Design of Frameworks with Mixed Triangular and Octahedral Building Blocks Exemplified by the Structure of [Zn4O(TCA)2] Having the Pyrite Topology   
2) Koh, K.; Wong-Foy, A.; Matzger, A.; J. Am. Chem. Soc., 2010, 132(42), 15005-15010, DOI: 10.1021/ja1065009 ; Coordination Copolymerization Mediated by Zn4O(CO2R)6 Metal Clusters: a Balancing Act between Statistics and Geometry 
3) Lee, E.; Jang, S.; Suh, M.; J. Am. Chem. Soc., 2005, 127(17), 6374-6381, DOI: 10.1021/ja043756x ; Multifunctionality and Crystal Dynamics of a Highly Stable, Porous Metal−Organic Framework [Zn4O(NTB)2] 
4) Wu, P.; He, C.; Wang, J.; Peng, X.; Li, X.; An, Y.; Duan, C.;  J. Am. Chem. Soc., 2012, 134(36), 14991-14999, DOI:10.1021/ja305367j
5) Li, C.; Xu, H.; Gao, J.; Du, W.; Shangguan, L.; Zhang, X.; Lin, R.; Wu, H.; Zhou, W.; Liu, X.; Yao, J.; Chen, B.;  J. Am. Chem. Soc., 2019, 7(19), 11928-11933, DOI: 10.1039/c9ta01942a
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