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5,5',5''-(benzene-1,3,5-triyltris(ethyne-2,1-diyl))triisophthalicacid

1,3,5-tris(3,5-dicarboxyphenylethynyl)benzene

CAS NO.:1173285-13-6Formula:C36H18O12Weight: 642.52092
Product Name:1,​3,​5-​tris(3,​5-​dicarboxylphenylethynyl)​benzene
Synonymous:btei;5,5′,5′′-benzene-1,3,5-triyltris(1-ethynyl-2-isophthalate)
CAS:1173285-13-6
Basic Info
M.F.  C36H18O12 M.W.  642.52
Appearance  
Properties
1) 1173285-13-6  is soluble in DMF and DMSO
2)  Sealed at room temperature
Appications
1) It could be used as monomer linker for MOF synthesis:PCN-61 [r1]; PMOF-​2(Zn) [r4]
Characterization
HNMR
MS
NA
FTIR
NA
HPLC
NA
Reference
1) Zhao, D.; Yuan, D.; Sun, D.; Zhou, H.; J. Am. Chem. Soc. 2009, 131, 26, 9186-9188, DOI: 10.1021/ja901109t ; Stabilization of Metal−Organic Frameworks with High Surface Areas by the Incorporation of Mesocavities with Microwindows  
2) Zheng, B.; Bai, J.; Duan, J.; Wojtas, L.; Zaworotko, M.; J. Am. Chem. Soc. 2011, 133, 4, 748-751, DOI: 10.1021/ja110042b ; Enhanced CO2 Binding Affinity of a High-Uptake rht-Type Metal−Organic Framework Decorated with Acylamide Groups  
3) Song, X.; Jeong, S.; Kim, D.; Lah, M.; CrystEngComm 2012, 14(18), 5753-5756, DOI: DOI:10.1039/c2ce26115d ; Transmetalations in two metal–organic frameworks with different framework flexibilities: Kinetics and core–shell heterostructure 
4) Hong, S.; Oh, M.; Park, M.; Yoon, J.; Chang, J.; Lah, M.; Chem. Commun. 2009, 36, 5397-5399, DOI: 10.1039/B909250A ; Large H2 storage capacity of a new polyhedron-​based metal-​organic framework with high thermal and hygroscopic stability
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